Investigation of Compatibility in Syndiotactic Poly(methyl methacrylate)/Poly(vinyl chloride) Blends

[en] Pulsed NMR and nonradiative energy transfer (NRET) measurements on blends of s-PMMA and PVC are described. Sources of the small-scale heterogeneity evident in all blends are discussed. Although it was not possible to arrive at a definitive model of this small-scale heterogeneity, consideration was given to factors which had important bearing on the miscibility achieved: (i) the method of mixing used and the relative sensitivity of the investigative techniques used, (ii) the effects of tacticity, molecular weight, and polydispersity on polymer-polymer miscibility, and (iii) the difference in the solubilization power of PVC for PMMA and PMMA for PVC. © 1985, American Chemical Society. All rights reserved.

Disciplines :

Chemistry

Author, co-author :

Albert, Brigitte; Université de Liège - ULiège

Jérôme, Robert ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Smyth, Gérard; Department of Pure and Applied Physics, Trinity College, University of Dublin, Dublin 2, Ireland, United States

Boyle, Noël G.; Department of Pure and Applied Physics, Trinity College, University of Dublin, Dublin 2, Ireland, United States

McBrierty, Vincent J.; Department of Pure and Applied Physics, Trinity College, University of Dublin, Dublin 2, Ireland, United States

Language :

English

Title :

Investigation of Compatibility in Syndiotactic Poly(methyl methacrylate)/Poly(vinyl chloride) Blends

Publication date :

1985

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society, United States - District of Columbia

Volume :

Issue :

Pages :

388-394

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 05 January 2020

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