Investigation of miscibility by spectroscopic methods IV. How far is poly(vinyl chloride) miscible with s‐poly(methyl methacrylate) and poly(styrene‐co‐acrylonitrile)? An answer from nonradiative energy transfer

Albert, Brigitte; Jérôme, Robert; Teyssié, Philippe

doi:10.1002/pola.1986.080240313

Article (Scientific journals)

Investigation of miscibility by spectroscopic methods IV. How far is poly(vinyl chloride) miscible with s‐poly(methyl methacrylate) and poly(styrene‐co‐acrylonitrile)? An answer from nonradiative energy transfer

Albert, Brigitte; Jérôme, Robert; Teyssié, Philippe

1986 • In Journal of Polymer Science. Part A, Polymer Chemistry, 24 (3), p. 551-558

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/242737

DOI
10.1002/pola.1986.080240313

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Keywords :

COPOLYMERS - Blending; FLUORESCENCE - Spectrum Analysis; PHOSPHORS - Applications; PLASTICS - Spectroscopic Analysis; POLYMETHYL METHACRYLATE - Blending; NONRADIATIVE ENERGY TRANSFER; POLY(STYRENE-CO-ACRYLONITRILE; POLYMER MISCIBILITY; POLYVINYL CHLORIDE

Abstract :

[en] Miscibility of PVC with s.PMMA and SAN, respectively, has been investigated by nonradiative energy transfer. Blended by using a common solvent, the two polymer pairs are not homogeneous at a molecular level. They are likely to contain heterogeneities of a few nanometers depending on blend composition. At a comparable number average molecular weight, but a different polydispersity, SAN is seemingly less miscible with PVC than s.PMMA. That this behavior is of enthalpic or entropic origin, or mainly due to the method of mixing, cannot be settled so far. Copyright © 1986 John Wiley & Sons, Inc.

Disciplines :

Chemistry

Author, co-author :

Albert, Brigitte; Université de Liège - ULiège

Jérôme, Robert ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

Publication date :

1986

Journal title :

Journal of Polymer Science. Part A, Polymer Chemistry

ISSN :

0887-624X

eISSN :

1099-0518

Publisher :

John Wiley & Sons, Hoboken, United States - New Jersey

Volume :

Issue :

Pages :

551-558

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 05 January 2020

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