[en] Lithium-sulfur batteries can displace lithium-ion by delivering higher specific energy. Presently, however, the superior energy performance fades rapidly when the sulfur electrode is loaded to the required levels\textemdash5 to 10 mg cm-2\textemdash due to substantial volume change of lithiation/delithiation and the resultant stresses. Inspired by the classical approaches in particle agglomeration theories, we found an approach that places minimum amounts of a high-modulus binder between neighboring particles, leaving increased space for material expansion and ion diffusion. These expansion-tolerant electrodes with loadings up to 15 mg cm-2 yield high gravimetric (\>1200 mA\textperiodcenteredhour g-1) and areal (19 mA\textperiodcenteredhour cm-2) capacities. The cells are stable for more than 200 cycles, unprecedented in such thick cathodes, with Coulombic efficiency above 99\%.
Disciplines :
Chemistry Energy Materials science & engineering
Author, co-author :
Shaibani, Mahdokht
Mirshekarloo, Meysam Sharifzadeh
Singh, Ruhani
Easton, Christopher D.
Cooray, M. C. Dilusha
Eshraghi, Nicolas ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
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