Butadiene 1,4 polymerization catalysis. II. An nmr study of the structure and dynamics of bis(η3-allylnickel trifluoroacetate) and its significance for the mechanism of the polymerization

Warin, Roger; Julémont, M.; Teyssié, Philippe

doi:10.1016/S0022-328X(00)83513-5

Article (Scientific journals)

Butadiene 1,4 polymerization catalysis. II. An nmr study of the structure and dynamics of bis(η3-allylnickel trifluoroacetate) and its significance for the mechanism of the polymerization

Warin, Roger; Julémont, M.; Teyssié, Philippe

1980 • In Journal of Organometallic Chemistry, 185 (3), p. 413-425

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https://hdl.handle.net/2268/242174

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10.1016/S0022-328X(00)83513-5

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Abstract :

[en] 1H NMR study of the molecular dynamics of bis(η3-allylnickel trifluoroacetate) has revealed not only the important role of the metalanion bond breaking in intra- and inter-molecular rearrangements but also stability of the η3-allyl coordination on the NMR time-scale. Implications for the mechanism of butadiene polymerization are discussed, and an interpretation of the control of the cistrans isomer ratio is tentatively proposed. © 1980.

Disciplines :

Chemistry

Author, co-author :

Warin, Roger ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie

Julémont, M.; Laboratory of Macromolecular Chemistry and Organic Catalysis, University of Liège, Sart Tilman, 4000 Liège, Belgium

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

Butadiene 1,4 polymerization catalysis. II. An nmr study of the structure and dynamics of bis(η3-allylnickel trifluoroacetate) and its significance for the mechanism of the polymerization

Publication date :

1980

Journal title :

Journal of Organometallic Chemistry

ISSN :

0022-328X

Publisher :

Elsevier, Netherlands

Volume :

185

Issue :

Pages :

413-425

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 12 December 2019

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