A vibrational assignment for biscyclooctatetraenyl metal complexes

[en] The structure of biscyclooctatetraenyl compounds (Ti, V, Th and U) is inferred from the results of i.r. spectra. We propose an assigmnent of the fundamental bands of these compounds based on qualitative results from the group theory. Some indications about the degree of ionicity of the metal ring bonds are also given. © 1974.

Disciplines :

Chemistry

Author, co-author :

Hocks, Léonard ; Institut de Chimie, Université de Liège, Sart Tilman par, 4000 Liège, Belgium

Goffart, J.; Institut de Chimie, Université de Liège, Sart Tilman par, 4000 Liège, Belgium

Duyckaerts, G.; Institut de Chimie, Université de Liège, Sart Tilman par, 4000 Liège, Belgium

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

A vibrational assignment for biscyclooctatetraenyl metal complexes

Publication date :

1974

Journal title :

Spectrochimica Acta.Part A, Molecular Spectroscopy

ISSN :

0584-8539

Publisher :

Pergamon Press, United Kingdom

Volume :

Issue :

Pages :

907-914

Peer reviewed :

Peer reviewed

Available on ORBi :

since 12 December 2019

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Bibliography

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Lippincott, Xavier, Steele J. Am. Chem. Soc. 1961, 83:2262.
Cyvin, Brunvoll, Shäffer J. Chem. Phys. 1971, 54:1517.
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Brunvoll, Cyvin, Schäffer (1972) Benzenechromium tricarbonyl III. Mean amplitudes of vibration and related quantities for C6H6Cr(CO)3. Journal of Organometallic Chemistry 36:137.
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Zalkin, Raymond J. Am. Chem. Soc. 1969, 91:5667.
Avdeef, Raymond, Hodgson, Zalkin (1972) Two isostructural actinide .pi. complexes. Crystal and molecular structure of bis(cyclooctatetraenyl)uranium(IV), U(C8H8)2, and bis(cyclooctatetraenyl)thorium(IV), Th(C8H8)2. Inorganic Chemistry 11:1083.
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Herzsberg Infrared and Raman Spectra of Polyatomic Molecules, Van Nostrand, New York; 1945.
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Hartley, Ware (1969) The vibrational spectra and assignment of bis-(?-cyclopentadienyl)-iron(II) and the bis-(?-cyclopentadienyl)cobalt(III) cation. Journal of the Chemical Society A: Inorganic, Physical, Theoretical 138.
Fritz Adv. in Organometall. Chem. 1964, 1:239.
Snyder (1972) On the infrared spectrum of dibenzene chromium. Spectrochimica Acta 15:807.
Fritz, Keller Z. Naturforsch. 1961, 16 b:231.
Fritz, Lüttke, Stammreich, Forneris Spectrochim. Acta 1961, 17:1068.
Mares, Hodgson, Streitwieser (1970) Lanthanide complexes with cyclooctatetraene di-anion. Journal of Organometallic Chemistry 24:C 68.
Nujent, Laubereau, Werner, Sluis (1971) Noncovalent character in the chemical bonds of the lanthanide(III)and the actinide(III) tricyclopentadienides. Journal of Organometallic Chemistry 27:365.
Cotton, Reynolds J. Am. Chem. Soc. 1958, 80:269.

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