[en] Organic electrode materials capable of reversible coordination/uncoordination of both mono- and multivalent ions in aqueous electrolytes are desired to develop safe, sustainable, and cost-effective water-based batteries. Here, we demonstrate the universality of bioinspired redox-active polymers bearing catechol pendants to reversibly coordinate/uncoordinate numerous cations including H+ and Li+ to Zn2+ and Al3+ with fast kinetics and ultralong cyclability. This unprecedented versatility is based on a catecholato–metal cation complex (Cat2–(mMn+)) charge storage mechanism that dictates the overall electrochemistry: formation of stronger complexes in M+ < M2+ < M3+ order resulted in a huge redox potential increment that might be used to tune the operating voltage of the battery.
Research Center/Unit :
CESAM - Complex and Entangled Systems from Atoms to Materials - ULiège Center for Education and Research on Macromolecules (CERM), Belgium
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Patil, Nagaraj; IMDEA Energy Institute, Electrochemical Processes Unit, Móstoles, Spain
Mavrandonakis, Andreas; IMDEA Energy Institute, Electrochemical Processes Unit, Móstoles, Spain
Jérôme, Christine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM), Belgium
Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM), Belgium
Palma, Jesus; IMDEA Energy Institute, Electrochemical Processes Unit, Móstoles, Spain
Marcilla, Rebeca; IMDEA Energy Institute, Electrochemical Processes Unit, Móstoles, Spain
Language :
English
Title :
Polymers bearing catechol pendants as universal hosts for aqueous rechargeable H+, Li-ion, and post-Li-ion (mono‑, di‑, and trivalent) batteries
Publication date :
28 May 2019
Journal title :
ACS Applied Energy Materials
eISSN :
2574-0962
Publisher :
American Chemical Society, United States
Volume :
2
Issue :
5
Pages :
3035-3041
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique MINECO - Gobierno de Espana. Ministerio de Economia y Competitividad CM - Comunidad de Madrid
Funding text :
We thank the Spanish MINECO (formerly MICINN) through the MAT2015-64167-C2-1-R project, the “Fonds de la Recherche Scientifique” (FRS-FNRS, Belgium), and the TALENTO grant (2017-T1/AMB-5264) from Comunidad de Madrid for financial support. We acknowledge the
computing facilities of CSUC for providing resources that contributed to the research results reported within this paper.
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