Atom transfer radical polymerisation (ATRP) and Kharasch addition mediated by titanium-ruthenium bimetallic systems

Numerous studies have been directed towards the synthesis of early-Iate
heterobimetallic complexes. Surprisingly, only few reports have been reported
about their catalytic behaviour. However, their potential in homogeneous catalysis
remains fantastic. Indeed, a cooperative work by the two metal centres in the
complex would lead to new catalytic systems with unique reactivity.