Poster (Scientific congresses and symposiums)
Hydrothermal dehydration of D-glucose and D-xylose in deionized water
Kammoun, Maroua; Istasse, Thibaut; Rassaa, Neila et al.
2018Maroua Kammoun
 

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Keywords :
hydroxymethylfurfural (5-HMF); furfural(2-F); monosaccharides
Abstract :
[en] The industrial trend is moving toward biobased plateform molecule preparation using biobased-processes integrating into green chemistry discipline. These “building blocks” molecules are intermediate for the synthesis of value-added chemicals. 5-hydroxymethylfurfural (5-HMF) and 2-furfural are two plateform molecules derived from monosaccharides. In order to produce these furanic compounds, xylose and glucose conversion were conducted in hot deionized water, which represent the greenest solvent, at 211°C, 20 bars by means of batch-type reactor. A selected rang of times T1= 1min, T2=15 min , T3=30 min ,T4=45 min and T5 =60 min were investigated. Results shows that at 15 min, the best 5-hydroxymethyl furfural ( 5- HMF) yield is 18,52%, produced by glucose dehydration, then it recorded a stable rate . At the same time 2-furfural was produced from xylose with a yield of 26,71% and didn’t vary significantly over time. A 11, 09 % and 9,67 % yield of Lactic acid (LA) and Fromic Acid (FA) were obtained as a co-product from glucose dehydration and 5.53 % of LA was generated from xylose decomposition.
Research center :
Laboratoire de Biomasse et Technologies Vertes
Disciplines :
Chemistry
Author, co-author :
Kammoun, Maroua ;  Université de Liège - ULiège > Gembloux Agro-Bio Tech
Istasse, Thibaut ;  Université de Liège - ULiège > Agronomie, Bio-ingénierie et Chimie (AgroBioChem) > SMARTECH
Rassaa, Neila
Bettaieb, Taoufik
Richel, Aurore  ;  Université de Liège - ULiège > Agronomie, Bio-ingénierie et Chimie (AgroBioChem) > SMARTECH
Language :
English
Title :
Hydrothermal dehydration of D-glucose and D-xylose in deionized water
Alternative titles :
[en] Hydrothermal dehydration of D-glucose and D-xylose in deionized water
Publication date :
04 May 2018
Number of pages :
76,6 cm *111,4 cm
Event name :
Maroua Kammoun
Event organizer :
Elsevier - Green and Sustainable Chemistry
Event place :
Berlin, Germany
Event date :
du 13 Mai 2018 au 16 Mai 2018
Audience :
International
Funders :
University of Carthage [TN]
Available on ORBi :
since 16 July 2018

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