[en] Optimal control theory has been employed to populate separately two dark states of the acetylene polyad, Ns = 1 and Nr =
5, by indirect coupling via the ground state. Relevant level energies and transition dipole moments are extracted from the
experimental literature. The optimal pulses are rather simple. The evolution of the population is shown for the duration
of the control process and also for the field-free evolution that follows the control. One of the dark states appears to be a
potential target for realistic experimental investigation because the average population of the Rabi oscillation remains high
and decoherence is expected to be weak.
Disciplines :
Chemistry
Author, co-author :
Santos, Ludovic
Iacobellis, Nicolas
Herman, Michel
Perry, David
Desouter, Michèle ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)
Vaeck, Nathalie
Language :
English
Title :
A test of optimal laser impulsion for controlling population within the Ns = 1, Nr = 5 polyad of 12C2H2
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