A test of optimal laser impulsion for controlling population within the Ns = 1, Nr = 5 polyad of 12C2H2

[en] Optimal control theory has been employed to populate separately two dark states of the acetylene polyad, Ns = 1 and Nr = 5, by indirect coupling via the ground state. Relevant level energies and transition dipole moments are extracted from the experimental literature. The optimal pulses are rather simple. The evolution of the population is shown for the duration of the control process and also for the field-free evolution that follows the control. One of the dark states appears to be a potential target for realistic experimental investigation because the average population of the Rabi oscillation remains high and decoherence is expected to be weak.

Disciplines :

Chemistry

Author, co-author :

Santos, Ludovic

Iacobellis, Nicolas

Herman, Michel

Perry, David

Desouter, Michèle ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Vaeck, Nathalie

Language :

English

Title :

A test of optimal laser impulsion for controlling population within the Ns = 1, Nr = 5 polyad of 12C2H2

Publication date :

2015

Journal title :

Molecular Physics

ISSN :

0026-8976

eISSN :

1362-3028

Publisher :

Taylor & Francis, London, United Kingdom

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 21 June 2018

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