[en] Optimal control theory has been employed to populate separately two dark states of the acetylene polyad, Ns = 1 and Nr =
5, by indirect coupling via the ground state. Relevant level energies and transition dipole moments are extracted from the
experimental literature. The optimal pulses are rather simple. The evolution of the population is shown for the duration
of the control process and also for the field-free evolution that follows the control. One of the dark states appears to be a
potential target for realistic experimental investigation because the average population of the Rabi oscillation remains high
and decoherence is expected to be weak.
Disciplines :
Chemistry
Author, co-author :
Santos, Ludovic
Iacobellis, Nicolas
Herman, Michel
Perry, David
Desouter, Michèle ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)
Vaeck, Nathalie
Language :
English
Title :
A test of optimal laser impulsion for controlling population within the Ns = 1, Nr = 5 polyad of 12C2H2
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Bibliography
C. Brif., R. Chakrabarti., and H. Rabitz., New J. Phys. 12, 075008 (2010).
C. Daniel., J. Full., L. González., C. Lupulescu., J. Manz., A. Merli., Š. Vajda., and L. Wöste., Science 299, 536 (2003).
C.P. Koch., J.P. Palao., R. Kosloff., and F. Masnou-Seeuws., Phys. Rev. A 70, 013402 (2004).
M.F. Kling., P. von den Hoff., I. Znakovskaya., and R. de Vivie-Riedle., Phys. Chem. Chem. Phys. 15, 9448 (2013).
D. Sugny., S. Vranckx., M. Ndong., N. Vaeck., O. Atabek., and M. Desouter-Lecomte., Phys. Rev. A 90, 053404 (2014).
W. Zhang., C. Shu., T. Ho., H. Rabitz., and S. Cong., J. Chem. Phys. 140, 094304 (2014).
Y. Kurosaki., T. Ho., and H. Rabitz., J. Chem. Phys. 140, 084305 (2014).
A. Chenel., C. Meier., G. Dive., and M. Desouter-Lecomte., J. Chem. Phys. 142, 024307 (2015).
B. Amyay., S. Robert., M. Herman., A. Fayt., B. Raghavendra., A. Moudens., J. Thievin., B. Rowe., and R. Georges., J. Chem. Phys. 131, 114301/1 (2009).
B. Amyay., M. Herman., A. Fayt., A. Campargue., and S. Kassi., J. Mol. Spectrosc. 267, 80 (2011).
M. Herman. and D.S. Perry., Phys. Chem. Chem. Phys. 15, 9970 (2013).
M. Herman., Mol. Phys. 105, 2217 (2007).
M. Herman., High-Resolution Infrared Spectroscopy of Acetylene: Theoretical Background and Research Trends (John Wiley and Sons Ltd,. Chichester, 2011), p. 1993.
B. Amyay., A. Fayt., and M. Herman., J. Chem. Phys. 135, 234305/1 (2011).
D.S. Perry., J. Martens., B. Amyay., and M. Herman., Mol. Phys. 110, 2687 (2012).
D.S. Perry., A. Miller., B. Amyay., A. Fayt., and M. Herman., Mol. Phys. 108, 1115 (2010).
J.M. Brown., J.T. Hougen., K.P. Huber., J.W.C. Johns., I. Kopp., H. Lefebvre-Brion., A.J. Merer., D.A. Ramsay., J. Rostas., and R.N. Zare., J. Mol. Spectrosc. 55, 500 (1975).
M. Herman., T.R. Huet., Y. Kabbadj., and J. Vander Auwera., Mol. Phys. 72, 75 (1991).
J. Vander Auwera., D. Hurtmans., M. Carleer., and M. Herman., J. Mol. Spectrosc. 157, 337 (1993).
B. Amyay., Ph. D. thesis, Université Libre de Bruxelles, 2012
D.B. Moss., Z. Duan., M.P. Jacobson., J.P. O'Brien., and R.W. Field., J. Mol. Spectrosc. 199, 265 (2000).
J. Werschnik. and E.K.U. Gross., J. Phys. B 40, R175 (2007).
K. Sundermann. and R. de Vivie-Riedle., J. Chem. Phys. 110, 1896 (1999).
W. Zhu., J. Botina., and H. Rabitz., J. Chem. Phys. 108, 1953 (1998).
C. Gollub., M. Kowalewski., and R. de Vivie-Riedle., Phys. Rev. Lett. 101, 073002 (2008).
E. Berrios., M. Gruebele., D. Shyshlov., L. Wang., and D. Babikov., J. Phys. Chem. A 116, 11347 (2012).
A.D. Bandrauk., Molecules in Laser Fields (CRC Press,. Boca Raton, FL, 1993), p. 109.
J.-P. Demailly., Analyse Numérique et Équations Différentielles (EDP Sciences,. Les Ulis, 2006), pp. 237-243.
W.H. Press., B.P. Flannery., S.A. Teukolsky., and W.T. Vetterling., Numerical Recipes in Fortran 77: The Art of Scientific Computing (Cambridge University Press, Cambridge, 1992), pp. 704-708.
D. Gabor., J. Inst. Elect. Eng. III 93, 429 (1946).
R.B. Blackman. and J.W. Tukey., The Measurement of Power Spectra, From the Point of View of Communications Engineering (Dover Publications,. New York, NY, 1959), pp. 98-99.
M.P. Jacobson. and R.W. Field., J. Phys. Chem. A 104, 3073 (2000)
S. Twagirayezu., M.J. Cich., T.J. Sears., C.P. McRaven., and G.E. Hall., J. Mol. Spectrosc. in press.
C.M. Tesch., L. Kurtz., and R. de Vivie-Riedle., Chem. Phys. Lett. 343, 633 (2001).
D. Shyshlov., E. Berrios., M. Gruebele., and D. Babikov., J. Chem Phys. 141, 224306 (2014).
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