Determination of PCDD/Fs and dl-PCBs in ash and particle samples generated by an incineration plant for hospital and industrial waste in Northern of Algeria

Kerchich, Yacine; Moussaoui, Yacine; Scholl, Georges; Eppe, Gauthier

doi:10.1016/j.apr.2018.01.017

Article (Scientific journals)

Determination of PCDD/Fs and dl-PCBs in ash and particle samples generated by an incineration plant for hospital and industrial waste in Northern of Algeria

Kerchich, Yacine; Moussaoui, Yacine; Scholl, Georges et al.

2018 • In Atmospheric Pollution Research Journal, (9), p. 968-975

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/219092

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10.1016/j.apr.2018.01.017

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Keywords :

dioxins; furans; PCBs; gas and particulate phase; clinical waste; Algeria

Abstract :

[en] PCDD/Fs and dl-PCB in ash and flue gas emission samples, generated by an incineration plant of clinical and industrial waste, were investigated at the sole incineration waste plant currently operating in Northern Algeria. We studied the incineration of six types of waste including bank notes, CD-ROM, clinical waste, sludge inks, expired pharmaceuticals and tobacco. For each of them, we collected gaseous emissions and ashes after incineration. Final extracts of the different wastes were analyzed by high-resolution gas chromatography coupled to high-resolution mass spectrometry (HRGC–HRMS). Flue gas results indicated that the emission concentrations of PCDD/Fs, expressed in I-TEQs, were in the range of 22.78 – 1647.86 pg I-TEQ Nm-3, while for dl-PCB in flue gas, expressed in WHO-TEQs, levels reported were between 0.66 – 46.97 pg WHO-TEQ Nm-3. Regarding incinerator ashes, levels span from 1.68 to 879.56 pg I-TEQ g-1 for PCDD/Fs and 0.1 to 28.30 pg WHO-TEQ g-1 for dl-PCBs. The contribution of dl-PCBs to the sum TEQ was relatively low for all matrices analyzed. A positive and consistent correlation was obtained between the 2,3,4,7,8-PeCDF concentration and I-TEQ PCDD/Fs values in flue gas and ash samples. XRF method was used to determine the major inorganic compounds that could be responsible of the inhibition of PCDD/Fs formation.

Research Center/Unit :

CART - Centre Interfacultaire d'Analyse des Résidus en Traces - ULiège
MolSys - Molecular Systems - ULiège

Disciplines :

Chemistry

Author, co-author :

Kerchich, Yacine

Moussaoui, Yacine

Scholl, Georges ; Université de Liège - ULiège > Département de chimie (sciences) > Center for Analytical Research and Technology (CART)

Eppe, Gauthier ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie analytique inorganique

Language :

English

Title :

Determination of PCDD/Fs and dl-PCBs in ash and particle samples generated by an incineration plant for hospital and industrial waste in Northern of Algeria

Publication date :

March 2018

Journal title :

Atmospheric Pollution Research Journal

eISSN :

1309-1042

Publisher :

Turkish National Committee for Air Pollution Research and Control, Izmir, Turkey

Issue :

Pages :

968-975

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 24 January 2018

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