Continuous-porous N-doped carbon network as high-performance electrode for lithium-ion batteries

Alkarmo, Walid; Ouhib, Farid; Aqil, Abdelhafid; Thomassin, Jean-Michel; Vertruyen, Bénédicte; Piedboeuf, Marie-Paule; Job, Nathalie; Detrembleur, Christophe; Jérôme, Christine

doi:10.1007/s10853-017-1974-9

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Article (Scientific journals)

Continuous-porous N-doped carbon network as high-performance electrode for lithium-ion batteries

Alkarmo, Walid; Ouhib, Farid; Aqil, Abdelhafid et al.

2018 • In Journal of Materials Science, 53 (8), p. 6135-6146

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/218868

DOI
10.1007/s10853-017-1974-9

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Keywords :

battery; composite

Abstract :

[en] Hierarchical porous N-doped carbon (NPC) is prepared by pyrolysis of poly(- methyl methacrylate) (PMMA) particles decorated by graphene oxide (GO) and polypyrrole (PPy) as precursors and used as anode for lithium-ion batteries. The composite precursors with different diameter and composition (PMMA/GO/ PPy-A and B) were conveniently prepared by dispersion polymerization of methyl methacrylate in the presence of graphene oxide as stabilizer in aqueous medium, followed by addition of pyrrole and its oxidative polymerization. After pyrolysis, the resulting NPC composites with hierarchically structured macro- and mesopores exhibit high surface area (289–398 m2/g) and different N-doping levels (7.46 and 4.22 wt% of nitrogen content). The NPC with the highest N-doping level (7.46 wt%) shows high reversible capacities of 831 mAh/g at 74.4 mA/g (C/5) after 50 cycles and excellent rate performances.

Research Center/Unit :

CESAM Complex and Entangled Systems from Atoms to Materials (CESAM)
Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Alkarmo, Walid ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Ouhib, Farid ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Aqil, Abdelhafid ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Thomassin, Jean-Michel ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Vertruyen, Bénédicte ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Group of Research in Energy and ENvironment from MATerials (Greenmat) and Laboratory of Structural Inorganic Chemistry (LCIS)

Piedboeuf, Marie-Paule; University of Liège (ULiège), Department of Chemical Engineering – Nanomaterials, Catalysis, Electrochemistry

Job, Nathalie ; University of Liège (ULiège), Department of Chemical Engineering – Nanomaterials, Catalysis, Electrochemistry

Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Continuous-porous N-doped carbon network as high-performance electrode for lithium-ion batteries

Publication date :

April 2018

Journal title :

Journal of Materials Science

ISSN :

0022-2461

eISSN :

1573-4803

Publisher :

Springer

Volume :

Issue :

Pages :

6135-6146

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Available on ORBi :

since 22 January 2018

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