Study of the structural and thermal stability of Li0.3Co2/3Ni1/6Mn1/6O2

[en] Abstract Thermal and structural stabilities of the delithiated positive electrode material LixCo2/3Ni1/6Mn1/6O2were studied by X-ray diffraction, magnetic and thermogravimetric analysis. In the opposite to the classical electrode materials LiNiO2 and LiCoO2, the structural symmetry (S.G. R-3m) of the starting material LiCo2/3Ni1/6Mn1/6O2 is preserved during the electrochemical cycling with a small variation of the unit cell parameters. Squid measurements evidenced that practically no Ni2+ ions were present in the lithium slab even after the lithium extraction process. For the thermal stability, the highly oxidized phase Li0.3Co2/3Ni1/6Mn1/6O2 was tested. This delithiated phase undergoes only 5.16% weight loss after heating up to 600°C. This weight loss has no effect on the structure symmetry as the starting α-NaFeO2 type structure was preserved during the thermal treatment. The obtained results coupled to the excellent electrochemical features of LiCo2/3Ni1/6Mn1/6O2clearly showits ability to compete with the commercialized cathode materials

Disciplines :

Chemistry

Author, co-author :

Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT

Saadoune, Ismael

Difi, Siham

Sougrati, Moulay Tahar

Lippens, Pierre-Emmanuel

Amarilla, José Manuel

Language :

English

Title :

Study of the structural and thermal stability of Li0.3Co2/3Ni1/6Mn1/6O2

Publication date :

2014

Journal title :

Electrochimica Acta

ISSN :

0013-4686

Publisher :

Pergamon Press - An Imprint of Elsevier Science

Volume :

135

Pages :

536 - 542

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science/article/pii/S0013468614010421

Available on ORBi :

since 15 January 2018

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M.R. PalacIn Chem, Recent advances in rechargeable battery materials: a chemist's perspective Soc. Rev. 38 2009 2565 2575
P. Tartaj, and J.M. Amarilla Porous inorganic nanostructures with colloidal dimensions: synthesis and applications in electrochemical energy devices Chem. Commun. 50 2014 2077 2088
G.G. Yadav, A. David, T. Favaloro, H. Yang, A. Shakouri, J. Caruthers, and Y. Wu Synthesis and investigation of thermoelectric and electrochemical properties of porous Ca9Co12O28nanowires J. Mater. Chem. A 1 2013 11901 11908
J.N. Reimers, and J.R. Dahn Electrochemical and In Situ X-Ray Diffraction Studies of Lithium Intercalation in LixCoO2 J. Electrochem. Soc. 139 8 1992 2091 2097 (Pubitemid 23578419)
T. Ohzuku, and A. Ueda Solid-State Redox Reactions of LiCoO2 (R3m) for 4 Volt Secondary Lithium Cells J. Electrochem. Soc. 141 11 1994 2972 2977
Y. Shao-Horn, S.A. Hackney, A.J. Kahaian, and M.M. Thackeray On The Low Temperature Stability of LiCoO2 Journal of Solid State Chemistry. 168 2002 60 68
D.D. MacNeil, L. Christensen, J. Landucci, J.M. Paulsen, and J.R. Dahn An Autocatalytic Mechanism for the Reaction of LixCoO2 in Electrolyte at Elevated Temperature J. Electrochem. Soc. 147 3 2000 970 979 (Pubitemid 30594883)
D.D. MacNeil, and J.R. Dahn Test of Reaction Kinetics Using Both Differential Scanning and Accelerating Rate Calorimetries As Applied to the Reaction of LixCoO2 in Non-aqueous Electrolyte J. of Phys. Chem. A. 105 2001 4430 4439
M. Dahbi, J.M. Wikberg, I. Saadoune, T. Gustafsson, P. Svedlindh, and K. Edström A delithiated LiNi0.65Co0.25Mn 0.10O2 electrode material: A structural, magnetic and electrochemical study Electrochem. Acta 54 2009 3211 3217
I. Saadoune, M. Ménétrier, and C. Delmas Redox processes in LixNi1-yCoyO2 cobalt-rich phases J. Mater. Chem. 7 2 1997 2505
H. Kageyama, H. Shigemura, M. Tabuchi, K. Ado, and H. Kobayashi XAFS study of LiCo1-xFexO2 cathode for rechargeable lithium battery by laboratory XAFS spectrometer J. Synchrotron Radiat. 1 8 2001 863 865 Pt, 2
M.S. Tomar, A. Hidalgo, P.S. Dobal, A. Dixit, R.E. Melgarejo, R.S. Katiyar, and K.A. Kuenhold A novel route for the synthesis of LiAl xCo1-xO2 battery materials and their structural properties Mater. Res. Soc. Symp. Proc. 658 2001 191
I. Saadoune, M. Labrini, M. Yahya, A. Almaggoussi, and H. Ehrenberg LiNi0.1Mn0.1Co0.8O2 electrode material: Structural changes upon lithium electrochemical extraction Electrochim. Acta. 55 2010 5180 5185
M. Labrini, I. Saadoune, A. Almaggoussi, J. Elhaskouri, and P. Amoros The LiyNi0.2Mn0.2Co0.6O2 electrode materials: A structural and magnetic study Mat. Res. Bull 47 2012 1004 1009
Q. Jianga, K. Duc, and Y. He A novel method for preparation of LiNi 1/3Mn1/3Co1/3O2 cathode material for Li-ion batteries ElectrochimicaActa 107 2013 133 138
R. Alcántara, P. Lavela, P.L. Relaño, and J.L. Tirado X-ray Diffraction, EPR, and 6Li and 27Al MAS NMR Study of LiAlO2 - LiCoO2 Solid Solutions Inorg. Chem. 37 1998 264 269 (Pubitemid 128483308)
M.M. Thackeray, S.-H. Kang, C.S. Johnson, J.T. Vaughey, and S.A. Hackney Comments on the structural complexity of lithium-rich Li1+xM 1-xO2 electrodes (M = Mn, Ni, Co) for lithium batteries Electrochem. Comm. 8 2006 1531 1538 (Pubitemid 44331694)
K.S. Park, A. Benayad, M.S. Park, W. Choi, and D. Im Suppression of O2 evolution from oxide cathode for lithium-ion batteries: VOx-impregnated 0.5Li2MnO3-0.5LiNi0.4Co 0.2Mn0.4O2 cathode Chem.Commun. 46 2010 4190 4192
A. Mahmoud, J.M. Amarilla, K. Lasri, and I. Saadoune Influence of the synthesis method on the electrochemical properties of the Li4Ti 5O12 spinel in Li-half and Li-ion full-cells: a systematic comparison Electrochim. Acta 93 2013 163 172
A. Mahmoud, I. Saadoune, J.M. Amarilla, and R. Hakkou On the LiCo 2/3Ni1/6Mn1/6O2 positive electrode material Electrochim. Acta. 56 2011 4081 4086
A. Mahmoud, M. Yoshita, I. Saadoune, J. Broetz, K. Fujimoto, and S. Ito LixCo0.4Ni0.3Mn0.3O2 electrode materials: Electrochemical and structural studies Mat. Res. Bull. 47 2012 1936 1941
Y. Bentaleb, I. Saadoune, K. Maher, L. Saadi, K. Fujimoto, and S. Ito On the LiNi0.2Mn0.2Co0.6O2 positive electrode material J. Power Sources. 195 2010 1510 1515
M. Aklalouch, R.M. Rojas, J.M. Rojo, and I. Saadoune The role of particle size on the electrochemical properties at 25 and 55 °C of the LiCr 0.2Ni0.4Mn1.4O4 spinel as 5V-cathode materials for lithium-ion batteries J.M. Amarilla, Electrochim. Acta. 54 2009 7542 7550
J. Rodriguez-Carvajal, Fullprof version January. 2006, Laboratoire Leon Brillouin, http://www-llb.cea.fr/fullweb/powder.htm.
J.B. Goodenough Magnetism and the Chemical Bond 1963 Interscience New York
J. Kanamori Superexchange interaction and symmetry properties of electron orbitals J. Phys. Chem. Solids. 10 1959 87 98
D. Linden, T.B. Reddy, "Handbook of Batteries," ed: McGraw-Hill Professional 2005.
J.R. Dahn, E.W. Fuller, M. Obrovac, and U. Von Sacken Thermal stability of LixCoO2, LixNiO2 and λ-MnO2 and consequences for the safety of Li-ion cells Solid State Ionics. 69 1994 265 270
M. Guilmard, L. Croguennec, D. Denux, and C. Delmas Chem. Mater. Thermal stability of lithium nickel oxide derivatives Part I: LixNi1.02O2 and LixNi0.89Al0.16O2 (x = 0.50 and 0.30) 15 2003 4476 4483
M. Ma, N.A. Chernova, P.Y. Zavalij, and M.S. Whittingham, "Structural and Electrochemical Properties of LiMn0.4Ni 0.4Co0.2O2," Mater. Res. Soc. Proc., 835, K11.3 (2005).
M. Dahbi, I. Saadoune, T. Gustafsson, and K. Edström Effect of manganese on the structural and thermal stability of Li0.3Ni 0.7-yCo0.3-yMn2yO2 electrode materials (y = 0 and 0.05) Solid State Ionics 203 2011 37 41
Y. Furushima, C. Yanagisawa, T. Nakagawa, Y. Aoki, and N. Muraki Thermal stability and kinetics of delithiated LiCoO2 J. Power Sources 196 2011 2260 2263
J.R. Dahn, E.W. Fuller, M. Obrovac, and U. von Sacken Thermal stability of LixCoO2, LixNiO2 and λ-MnO2 and consequences for the safety of Li-ion cells Solid State Ionics 69 1994 265 270