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Article (Scientific journals)
On the LiCo2/3Ni1/6Mn1/6O2 positive electrode material
Mahmoud, Abdelfattah; Saadoune, Ismael; Amarilla, José Manuel et al.
2011 • In Electrochimica Acta, 56 (11), p. 4081 - 4086
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https://hdl.handle.net/2268/218228
DOI
10.1016/j.electacta.2011.01.118
 

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Keywords :
Lithium-ion batteries; Layered oxide; Combustion method; LiCoNiMnO
Abstract :
[en] Abstract LiCo2/3Ni1/6Mn1/6O2 layered oxide was synthesized by the combustion method that led to a crystalline phase with good homogeneity and low particles size. The structural properties of the prepared positive electrode material were investigated by performing XRD Rietveld refinement. Practically no Li/Ni mixing was detected evidencing that the studied compound adopts almost an ideal α-NaFeO2 type structure. The Li||LiCo2/3Ni1/6Mn1/6O2 cell showed a discharge capacity of 199mAhg−1 when cycled in the 2.7–4.6V potential range while the best cycling performances were recorded when the upper cut off is fixed at 4.5V. Structural changes in LixCo2/3Ni1/6Mn1/6O2 with lithium electrochemical de-intercalation were studied using X-ray diffraction. This study clearly shows the existence of a solid solution domain in the 0.1
Disciplines :
Chemistry
Author, co-author :
Mahmoud, Abdelfattah  ;  Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Saadoune, Ismael
Amarilla, José Manuel
Hakkou, Rachid
Language :
English
Title :
On the LiCo2/3Ni1/6Mn1/6O2 positive electrode material
Publication date :
2011
Journal title :
Electrochimica Acta
ISSN :
0013-4686
eISSN :
1873-3859
Publisher :
Pergamon Press - An Imprint of Elsevier Science
Volume :
56
Issue :
11
Pages :
4081 - 4086
Peer reviewed :
Peer Reviewed verified by ORBi
Additional URL :
http://www.sciencedirect.com/science/article/pii/S0013468611001927
Funders :
CNRST Morocco/CSIC Spain (project 2010-2011)
Available on ORBi :
since 15 January 2018

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