Reference : Macroporous poly(ionic liquid)/ionic liquid gels via CO2-based emulsion-templating po...
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/217072
Macroporous poly(ionic liquid)/ionic liquid gels via CO2-based emulsion-templating polymerization
English
Mathieu, Kevin [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
Jérôme, Christine mailto [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
Debuigne, Antoine mailto [University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > > > >]
28-Jan-2018
Polymer Chemistry
Royal Society Chemistry
9
4
428-437
Yes (verified by ORBi)
International
1759-9954
1759-9962
Cambridge
United Kingdom
[en] supercritical carbon dioxide ; poly(ionic liquid) ; foam
[en] Structuring poly(ionic liquid)s (PILs) into porous materials or swelling PILs with free ionic liquids (ILs) has received specific attention recently and contributed to improve the performances of these materials used in a wide range of applications. The present work aims to take benefit of both approaches and produce macroporous PIL/IL gels in a single step through an innovative emulsion-templated polymerization method based on supercritical carbon dioxide (scCO2). More precisely, ILs vinyl monomers and crosslinkers were polymerized in the presence of non polymerizable ILs within the outer phase of a CO2-in-ILs high internal phase emulsion (HIPE). Specific macromolecular surfactants were synthesized by controlled radical polymerization techniques and tested for the stabilization of the CO2-in-ILs emulsions. While optimizing the polymerization conditions, we found that adding a limited amount of water in the medium was beneficial for the emulsion stability. Overall, this straightforward process gave access to macroporous polyHIPEs composed of poly(vinyl imidazolium) networks swollen by ‘free’ vinyl imidazolium-based ILs having interesting properties such as switchable polarity upon simple anion exchange reaction.
CESAM Complex and Entangled Systems from Atoms to Materials (CESAM) ; Center for Education and Research on Macromolecules (CERM)
Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Researchers
http://hdl.handle.net/2268/217072
10.1039/C7PY01952A

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