[en] n-tetrabutyl ammonium organic salts are used for the first time as catalysts for the coupling of CO2 with 2-methyl-3-butyn-2-ol to form α-methylene cyclic carbonate. The final yields could reach 98% in less than 10 hours at 353K and 3MPa under solvent free conditions. A particular synergistic effect between the cation and the anion of the organocatalyst is demonstrated through catalyst screening. Online kinetic studies by ATR-IR spectroscopy correlated to DFT calculations reveal a compelling evolution of the solvation of the catalyst during the reaction that provide an understanding of the underlying reason for the observed unique kinetics and selectivity. Such in-depth fundamental mechanistic and kinetic studies enable determining and comprehending the key parameters favouring the design of novel highly active and selective catalysts for the valorisation
Research Center/Unit :
CESAM Complex and Entangled Systems from Atoms to Materials (CESAM) Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Méreau, Raphaël; University of Bordeaux, CNRS, Institute of Molecular Sciences, Talence, France
Grignard, Bruno ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Boyaval, Amélie ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM) > University of Bordeaux, CNRS, Institute of Molecular Sciences, Talence, France
Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)
Tassaing, Thierry; University of Bordeaux, CNRS, Institute of Molecular Sciences, Talence, France
Language :
English
Title :
Tetrabutyl ammonium salts: cheap catalysts for the facile and selective synthesis of a-alkylidene cyclic carbonates from CO2 and alkynol
Publication date :
07 March 2018
Journal title :
ChemCatChem
ISSN :
1867-3880
eISSN :
1867-3899
Publisher :
Wiley, Weinheim, Germany
Volume :
10
Issue :
5
Pages :
956-960
Peer reviewed :
Peer Reviewed verified by ORBi
Name of the research project :
The Walloon Region through the "Flycoat" and "CO2Green" projects
Funders :
Walloon region BELSPO - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique Conseil Régional d'Aquitaine The International Doctoral School IDS-Funmat
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