Reference : Comparison of Different Ion Mobility Setups using Poly(ethylene oxide) PEO Polymers: ...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/215125
Comparison of Different Ion Mobility Setups using Poly(ethylene oxide) PEO Polymers: Drift Tube, TIMS and T-Wave
English
Haler, Jean mailto [Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.) >]
Massonnet, Philippe mailto [Université de Liège - ULiège > Département de chimie (sciences) > Center for Analytical Research and Technology (CART) >]
Chirot, Fabien mailto [Université de Lyon > Institut des Sciences Analytiques > > >]
Kune, Christopher mailto [Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.) >]
Comby-Zerbino, Clothilde mailto [Université de Lyon > Institut Lumière Matière > > >]
Jordens, Jan mailto [DSM > DSM Resolve > > >]
Honing, Maarten mailto [DSM > DSM Resolve > > >]
Mengerink, Ynze mailto [DSM > DSM Resolve > > >]
Far, Johann mailto [Université de Liège - ULiège > Département de chimie (sciences) > Center for Analytical Research and Technology (CART) >]
Dugourd, Philippe mailto [Université de Lyon > Institut Lumière Matière > > >]
De Pauw, Edwin mailto [Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.) >]
2018
Journal of the American Society for Mass Spectrometry
Elsevier Science
29
1
114-120
Yes (verified by ORBi)
International
1044-0305
1879-1123
New York
NY
[en] Ion mobility ; Mass spectrometry ; TIMS ; Drift tube ; Traveling wave ; Synthetic polymers ; Poly(ethylene oxide)
[en] Over the years, polymer analyses using ion mobility-mass spectrometry (IM-MS) measurements have been performed on different ion mobility spectrometry (IMS) setups. In order to be able to compare literature data taken on different IM(-MS) instruments, ion heating and ion temperature evaluations have already been explored. Nevertheless, extrapolations to other analytes are difficult and thus straightforward same-sample instrument comparisons seem to be the only reliable way to make sure that the different IM(-MS) setups do not greatly change the gas phase behavior. We used a large range of degrees of polymerization (DP) of poly(ethylene oxide) PEO homopolymers to measure IMS drift times on three different IM-MS setups: a homemade drift tube (DT), a trapped (TIMS) and a travelling wave (T-Wave) IMS setup. The drift time evolutions were followed for increasing polymer DPs (masses) and charge states and they are found to be comparable and reproducible on the three instruments.
Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Researchers ; Professionals ; Students
http://hdl.handle.net/2268/215125
10.1007/s13361-017-1822-9
https://link.springer.com/article/10.1007%2Fs13361-017-1822-9
http://rdcu.be/wIgG
FP7 ; 320659 - LASER-IMS - Coupling laser spectroscopy to mass spectrometry and ion mobility: from fundamentals to analytical sciences

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