[en] Extraction is a downstream-process option in bio-based processes. Since the knowledge of phase-separation behavior is essential for designing efficient separation processes, this study investigates the settling and coalescence behavior of bio-based extraction systems using a standard lab-scale settling cell. The influence of
different buffer media as well as of E. coli cells on coalescence was determined for the reactive extraction of hexane-1.6-diamine with isostearic acid and D2EHPA using kerosene and oleyl alcohol as diluents. As a result, an increasing pH value of the buffer significantly increases settling time. The presence of E. coli cells hinders the phase separation of the investigated systems, in particular with dispersed organic phases.
Centre/Unité de recherche :
PEPs, Products, Environment, and Processes, Department of Chemical Engineering
Disciplines :
Ingénierie chimique
Auteur, co-auteur :
Bednarz, Andreas
Scherübel, Peter
Spieß, Antje C.
Pfennig, Andreas ; Université de Liège > Department of Chemical Engineering > PEPs - Products, Environment, and Processes
Langue du document :
Anglais
Titre :
Optimization of settling behavior for an efficient solvent-extraction process for bio-based components
P. Frenzel, S. Fayyaz, R. Hillerbrand, A. Pfennig, Chem. Eng. Technol. 2013, 36 (2), 233–240. DOI: 10.1002/ceat.201200302
P. Frenzel, R. Hillerbrand, A. Pfennig, Polymer 2014, 6 (2), 327–345. DOI: 10.3390/polym6020327
P. Frenzel, R. Hillerbrand, A. Pfennig, Chem. Eng. Res. Des. 2014, 92 (10), 2006–2015. DOI: 10.1016/j.cherd.2013.12.024
T. Lindl, G. Gstraunthaler, Zell- und Gewebekultur: Allgemeine Grundlagen und spezielle Anwendungen, 7th ed., Springer, Berlin 2013.
L. J. Bruce, A. J. Daugulis, Biotechnol. Prog. 1991, 7 (2), 116–124. DOI: 10.1021/bp00008a006
J. Sikkema, J. A. M. de Bont, B. Poolman, J. Biol. Chem. 1994, 269 (11), 8022–8028.
Z. Gu, B. A. Glatz, C. E. Glatz, Biotechnol. Bioeng. 1998, 57, 454–461. DOI: 10.1002/(SICI)1097-0290(19980220)57:4<454::AID-BIT9>3.0.CO;2-L
C. Job, C. Schertler, W. L. Staudenbauer, E. Blass, Biotechnol. Tech. 1989, 3 (5), 315–320. DOI: 10.1007/BF01875628
C. Laane, S. Boeren, K. Vos, C. Veeger, Biotechnol. Bioeng. 1987, 30 (1), 81–87. DOI: 10.1002/bit.260300112
J. A. M. de Bont, Trends Biotechnol. 1998, 16 (12), 493–499. DOI: 10.1016/S0167-7799(98)01234-7
J. Sangster, Octanol-Water Partition Coefficients: Fundamentals and Physical Chemistry, Wiley Series in Solution Chemistry, Vol. 2, John Wiley & Sons, Chichester 1997.
T. Eggeman, D. Verser, in Proc. of the Twenty-Sixth Symposium on Biotechnology for Fuels and Chemicals (Eds: B. H. Davison, B. R. Evans, M. Finkelstein, J. D. McMillan), Humana Press, Totowa, NJ 2005.
D. Maass, M. R. Gerigk, A. Kreutzer, D. Weuster-Botz, M. Wubbolts, R. Takors, Bioprocess Biosyst. Eng. 2002, 25 (2), 85–96. DOI: 10.1007/s00449-002-0279-8
E. Alkaya, S. Kaptan, L. Ozkan, S. Uludag-Demirer, G. N. Demirer, Chemosphere 2009, 77 (8), 1137–1142. DOI: 10.1016/j.chemosphere.2009.08.027
T. Kurzrock, D. Weuster-Botz, Bioprocess Biosyst. Eng. 2011, 34 (7), 779–787. DOI: 10.1007/s00449-011-0526-y
M. Anvari, G. Khayati, J. Ind. Microbiol. Biotechnol. 2009, 36 (2), 313–317. DOI: 10.1007/s10295-008-0501-z
Z. Likidis, K. Schügerl, J. Biotechnol. 1987, 5 (4), 293–303. DOI: 10.1016/0168-1656(87)90026-5
C. Job, E. Blass, Chem. Eng. J. 1994, 56 (1), B1–B8. DOI: 10.1016/0923-0467(94)87025-X
J. A. Tamada, A. S. Kertes, C. J. King, Ind. Eng. Chem. Res. 1990, 29 (7), 1319–1326. DOI: 10.1021/ie00103a035
K. H. Hong, W. H. Hong, D. H. Han, Biotechnol. Bioprocess Eng. 2001, 6, 386–394. DOI: 10.1007/BF02932319
D. Hollmann, J. Switalski, S. Geipel, U. Onken, J. Ferment. Bioeng. 1995, 79 (6), 594–600. DOI: 10.1016/0922-338X(95)94754-F
S. Kumar, B. V. Babu, Chem. Biochem. Eng. Q. 2009, 23 (3), 367–376.
R. Wennersten, J. Chem. Technol. Biotechnol. 1983, 33 (2), 85–94. DOI: 10.1002/jctb.280330202
J. Zigova, E. Sturdik, D. Vandak, S. Schlosser, Process Biochem. 1999, 34 (8), 835–843. DOI: 10.1016/S0032-9592(99)00007-2
İ. İnci, Y. S. Aşçi, A. F. Tuyun, E-J. Chem. 2011, 8 (S1), S509–S515. DOI: 10.1155/2011/167945
C. S. López-Garzón, A. J. Straathof, Biotechnol. Adv. 2014, 32 (5), 873–904. DOI: 10.1016/j.biotechadv.2014.04.002
A. Jaquet, L. Quan, I. Marison, U. von Stockar, J. Biotechnol. 1999, 68 (2–3), 185–196. DOI: 10.1016/S0168-1656(98)00200-4
Y. S. Huh, Y. K. Hong, W. H. Hong, H. N. Chang, Biotechnol. Lett. 2004, 26 (20), 1581–1584. DOI: 10.1023/B:BILE.0000045656.00138.93
Y. K. Hong, W. H. Hong, Sep. Purif. Technol. 2005, 42 (2), 151–157. DOI: 10.1016/j.seppur.2004.03.015
T. Kurzrock, D. Weuster-Botz, Biotechnol. Lett. 2010, 32 (3), 331–339. DOI: 10.1007/s10529-009-0163-6
P. von Frieling, K. Schügerl, Process Biochem. 1999, 34 (6–7), 685–696. DOI: 10.1016/S0032-9592(98)00143-5
R. Chen, Y. Y. Lee, Appl. Biochem. Biotechnol. 1997, 63–65 (1), 435–448. DOI: 10.1007/BF02920444
M. Järvinen, L. Myllykoski, R. Keiski, J. Sohlo, Bioseparation 2000, 9 (3), 163–166. DOI: 10.1023/A:1008183322075
J. Zhou, W. Bi, K. H. Row, Korean J. Chem. Eng. 2011, 28 (7), 1608–1612. DOI: 10.1007/s11814-011-0010-z
M.-T. Gao, T. Shimamura, N. Ishida, E. Nagamori, H. Takashi, S. Umemoto, T. Omasa, H. Ohtake, Enzyme Microb. Technol. 2009, 44 (5), 350–354. DOI: 10.1016/j.enzmictec.2008.12.001
N. Tik, E. Bayraktar, Ü. Mehmetoglu, J. Chem. Technol. Biotechnol. 2001, 76 (7), 764–768. DOI: 10.1002/jctb.449
A. Bednarz, A. C. Spieß, A. Pfennig, J. Chem. Technol. Biotechnol. 2017, 92 (7), 1817–1824. DOI: 10.1002/jctb.5183
A. Bednarz, B. Rüngeler, A. Pfennig, Chem. Ing. Tech. 2014, 86 (5), 611–620. DOI: 10.1002/cite.201300115
A. Pfennig, T. Pilhofer, J. Schröter, in Fluidverfahrenstechnik (Ed: R. Goedecke), Wiley-VCH, Weinheim 2006.
L. H. Schlieper, M. Chatterjee, M. Henschke, A. Pfennig, AIChE J. 2004, 50 (4), 802–811.
M. Henschke, L. H. Schlieper, A. Pfennig, Chem. Eng. J. 2002, 85 (2–3), 369–378. DOI: 10.1016/S1385-8947(01)00251-0
M. A. Eitemann, J. L. Gainer, Appl. Microbiol. Biotechnol. 1989, 30 (6), 614–618. DOI: 10.1007/BF00255368
C. Job, E. Blass, in Solvent Extraction 1990 – Part B (Ed: T. Sekine), Process Metallurgy, Vol. 7B, Elsevier Science, Amsterdam 1990, 1893.
T. Kurzrock, S. Schallinger, D. Weuster-Botz, Biotechnol. Prog. 2011, 27 (6), 1623–1628. DOI: 10.1002/btpr.673
A. S. Heeres, C. S. F. Picone, L. A. M. van der Wielen, R. L. Cunha, M. C. Cuellar, Trends Biotechnol. 2014, 32 (4), 221–229. DOI: 10.1016/j.tibtech.2014.02.002
H. Firoozmand, D. Rousseau, Food Res. Int. 2016, 81, 66–73. DOI: 10.1016/j.foodres.2015.10.018
T. C. P. Moreira, V. M. da Silva, A. K. Gombert, R. L. da Cunha, Colloids Surf., B 2016, 143, 399–405. DOI: 10.1016/j.colsurfb.2016.03.043
G. F. Furtado, C. S. F. Picone, M. C. Cuellar, R. L. Cunha, Colloids Surf., B 2015, 128, 568–576. DOI: 10.1016/j.colsurfb.2015.03.010
A. Krzyżaniak, B. Schuur, A. B. de Haan, J. Chem. Technol. Biotechnol. 2013, 88 (10), 1937–1945. DOI: 10.1002/jctb.4058
A. Krzyżaniak, A. Tansaz, B. Schuur, A. B. de Haan, J. Chem. Technol. Biotechnol. 2014, 89 (7), 1015–1022. DOI: 10.1002/jctb.4193
M. Henschke, Dissertation, RWTH Aachen 1995.
N. Kopriwa, A. Pfennig, Solvent Extr. Ion Exch. 2016, 34 (7), 622–642. DOI: 10.1080/07366299.2016.1244392
S. U. Pickering, J. Chem. Soc., Trans. 1907, 91, 2001–2021. DOI: 10.1039/CT9079102001
R. Ramsden, Proc. R. Soc. London 1903, 72, 156–164.
S. Ruckes, Dissertation, RWTH Aachen 2015.
S. Ruckes, A. Pfennig, 19th Int. Solvent Extraction Conf., Santiago de Chile, October 2011.
J. H. Schulman, J. Leja, Trans. Faraday Soc. 1954, 50, 598–605. DOI: 10.1039/tf9545000598
