[en] A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.
Disciplines :
Chemistry
Author, co-author :
Naik, Anil; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences, Molecules, Solids, Reactivity (IMCN/MOST),
Robeyns, Koen; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences, Molecules, Solids, Reactivity (IMCN/MOST)
Meunier, Christophe; Université de Namur - UNamur > Laboratoire de Chimie des Matériaux Inorganiques (CMI)
Léonard, Alexandre ; Université de Liège > Department of Chemical Engineering > Ingéniérie électrochimique
Rotaru, Aurelien; “Stefan cel Mare” University > Department of Electrical Engineering and Computer Science
Tinant, Bernard; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences, Molecules, Solids, Reactivity (IMCN/MOST)
Filinchuk, Yaroslav; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences, Molecules, Solids, Reactivity (IMCN/MOST)
Su, Bao-Lian; Université de Namur - UNamur > Laboratoire de Chimie des Matériaux Inorganiques (CMI)
Garcia, Yann; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences, Molecules, Solids, Reactivity (IMCN/MOST)
Language :
English
Title :
Selective and Reusable Iron(II)-Based Molecular Sensor for the Vapor-Phase Detection of Alcohols
Publication date :
2014
Journal title :
Inorganic Chemistry
ISSN :
0020-1669
eISSN :
1520-510X
Publisher :
American Chemical Society, Washington, United States - District of Columbia
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Van Duyne, R. P.; Hupp, J. T. Chem. Rev. 2012, 112, 1105
Gütlich, P.; Gaspar, A. B.; Garcia, Y. Beilstein J. Org. Chem. 2013, 9, 342
Coronado, E.; Gimenez-Marques, M.; Minguez Espallargas, G.; Rey, F.; Vitorica-Yrezabal, I. J. J. Am. Chem. Soc. 2013, 135, 15986
Arcís-Castillo, Z.; Muñoz-Lara, F. J.; Muñoz, M. C.; Aravena, D.; Gaspar, A. B.; Sánchez-Royo, J. F.; Ruiz, E.; Ohba, M.; Matsuda, R.; Kitagawa, S.; Real, J. A. Inorg. Chem. 2013, 52, 12777
Hadler, G. J.; Kepert, C. J.; Moubaraki, B.; Murray, K. S.; Cashion, J. D. Science 2002, 298, 1762
Neville, S.; Halder, G.; Chapman, K.; Duriska, M.; Southon, P.; Cashion, J.; Létard, J. F.; Moubaraki, B.; Murray, K.; Kepert, C. J. Am. Chem. Soc. 2008, 130, 2869
Ohba, M.; Yoneda, K.; Agustí, G.; Muñoz, M. C.; Gaspar, A. B.; Real, J. A.; Yamasaki, M.; Ando, H.; Nakao, Y.; Sakaki, S.; Kitagawa, S. Angew. Chem., Int. Ed. 2009, 48, 4767
Naik, A. D.; Marchand-Brynaert, J.; Garcia, Y. Synthesis 2008, 1, 149
Gütlich, P.; Garcia, Y. In Mössbauer Spectroscopy; Yoshida, Y.; Langouche, G., Eds.; Springer: Berlin, 2013; Chapter 2, pp 23-89.
Robert, F.; Naik, A. D.; Tinant, B.; Robiette, R.; Garcia, Y. Chem.-Eur. J. 2009, 15, 4327
Varret, F.; Slimani, A.; Boukheddaden, K.; Chong, C.; Mishra, H.; Collet, E.; Haasnoot, J. G.; Pillet, S. New J. Chem. 2011, 35, 2333
Niel, V.; Thompson, A. L.; Muñoz, M. C.; Galet, A.; Goeta, A. E.; Real, J. A. Angew. Chem., Int. Ed. 2003, 42, 3760
Ito, H.; Muromoto, M.; Kurenuma, S.; Ishizaka, S.; Kitamura, N.; Sato, H.; Seki, T. Nat. Commun. 2013, 4, 2009
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.
