Reference : Macromolecular engineering of aliphatic polyesters by ring-opening polymerization
Scientific congresses and symposiums : Unpublished conference/Abstract
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/20908
Macromolecular engineering of aliphatic polyesters by ring-opening polymerization
English
Lecomte, Philippe mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
9-Sep-2008
No
Yes
International
NATO Advanced Study Intstitute (ASI), New Smart Materials via metal mediated macromolecular engineering: from complex to nano structures
1/09/2008 - 12/01/2008
Khosravi Ezat
Yagci Yusuf
Savelyev Yuri
Antalya
Turkey
[en] ring-opening polymerization (ROP) ; lactone
[en] During the past few years, a steadily increasing attention was paid to the synthesis of biodegradable and biocompatible aliphatic polyesters because of potential applications as biomaterials or as environmentally friendly thermoplastics. The first purpose of this work is to show that the modification of these aliphatic polyesters by pendant functional groups is an efficient tool to tailor the main properties, including biodegradation rate, bioadhesion, hydrophilicity, degree of crystallinity. The strategies implemented for the synthesis of aliphatic polyesters bearing pendant functional groups rely on the synthesis of g-substituted e-caprolactones followed by their ring-opening polymerization and on the chemical modification of duly functionalized aliphatic polyesters.The second part of the lecture will be dedicated to some recent examples dealing with the use of functional caprolactones to prepare various architectures such as star-shaped copolymers, graft copolymers, macrocycles and networks.
Center for Education and Research on Macromolecules (CERM)
Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/20908
This oral communication was presented by Philippe Lecomte

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