Magnetocaloric Properties of Zinc-Nickel Ferrites Around Room Temperature

El Maalam, Khadija; Fkhar, lahcen; Mohammed, Hamedoun; Mahmoud, Abdelfattah; Boschini, Frédéric; Hlil, E. K.; Benyoussef, Abdelilah; Mounkachi, Omar

doi:10.1007/s10948-016-3961-9

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Magnetocaloric Properties of Zinc-Nickel Ferrites Around Room Temperature

El Maalam, Khadija; Fkhar, lahcen; Mohammed, Hamedoun et al.

2017 • In Journal of Superconductivity and Novel Magnetism, p. 1-5

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/207525

DOI
10.1007/s10948-016-3961-9

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Keywords :

Spinel ferrites; Magnetocaloric; Solid-state reaction; Curie temperature; Isothermal entropy change

Abstract :

[en] In this paper, structural, magnetic, and magnetocaloric properties of zinc-doped nickel ferrite, Zn1−xNixFe2O4 (x = 0.3 and 0.4) were investigated. The samples were prepared using solid-state reaction. X-ray diffraction (XRD) and magnetization measurements were performed to study crystallographic structure and magnetic properties. For a magnetic field changing from 0 to 5 T, the corresponding isothermal entropy change was found to be near 1.4 J/kg K for both samples. The decreasing of Ni content from x = 0.4 to 0.3, enables to shift the Curie temperature of Zn1−xNixFe2O4 from 450 K toward (325 K). As main results, it was found that the relative cooling power (RCP) could be significantly enhanced by changing Ni concentration in Zn1−xNixFe2O4 (505 J/kg (for x = 0.3) and 670 J/kg (for x = 0.4)), which is considered as a recommended parameter for a wide temperature range in magnetic refrigeration application. Our finding should inspire and open new ways for the enhancement of the magnetocaloric effect in spinel ferrite-based materials.

Disciplines :

Chemistry

Author, co-author :

El Maalam, Khadija

Fkhar, lahcen

Mohammed, Hamedoun

Mahmoud, Abdelfattah ; Université de Liège > Département de chimie (sciences) > LCIS - GreenMAT

Boschini, Frédéric ; Université de Liège > Plateforme APTIS

Hlil, E. K.

Benyoussef, Abdelilah

Mounkachi, Omar

Language :

English

Title :

Magnetocaloric Properties of Zinc-Nickel Ferrites Around Room Temperature

Publication date :

14 February 2017

Journal title :

Journal of Superconductivity and Novel Magnetism

ISSN :

1557-1939

eISSN :

1557-1947

Publisher :

Springer, Germany

Pages :

1-5

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 21 February 2017

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