The design and study of new Li-ion full cells of LiCo2/3Ni1/6Mn1/6O2 positive electrode paired with MnSn2 and Li4Ti5O12 negative electrodes

Mahmoud, Abdelfattah; Saadoune, Ismael; Lippens, Pierre-Emmanuel; Chamas, Mohamad; Hakkou, Rachid; José Manuel, Amarilla

doi:10.1016/j.ssi.2016.12.012

Article (Scientific journals)

The design and study of new Li-ion full cells of LiCo2/3Ni1/6Mn1/6O2 positive electrode paired with MnSn2 and Li4Ti5O12 negative electrodes

Mahmoud, Abdelfattah; Saadoune, Ismael; Lippens, Pierre-Emmanuel et al.

2017 • In Solid State Ionics, 300, p. 175-181

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/207148

DOI
10.1016/j.ssi.2016.12.012

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Keywords :

lithium-ion batteries; electrode material; full cell; oxide; alloy

Abstract :

[en] We report evidence for the electrochemical performances of two Li-ion full cells, built up by the combination of LiCo2/3Ni1/6Mn1/6O2 cathode material with MnSn2 intermetallic and Li4Ti5O12 spinel as the anode materials, respectively. MnSn2 and Li4Ti5O12 electrode materials illustrate different working voltage versus the redox couple Li+/Li0 and different reactionmechanisms during lithiuminsertion/deinsertion cycles. The structure,morphological characteristics and the electrochemical properties of the studied materialswere investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical techniques. The two full-cell configurations showed different electrochemical behaviors. The MnSn2//LiCo2/3Ni1/6Mn1/6O2 configuration exhibits high working voltage (~3.5 V) and specific capacity (~200 mAh/gcathode) but suffers from high irreversible capacity loss during the first cycles and capacity fading during cycling. The Li4Ti5O12//LiCo2/3Ni1/6Mn1/6O2 cell demonstrated excellent cycling properties at different C-rates with 100% capacity retention after 150 cycles at 1 C. Although the working voltage (~2.2 V) and the specific capacity (~140 mAh/gcathode) are lower than those of the MnSn2//LiCo2/3Ni1/6Mn1/6O2 configuration, the other measured electrochemical properties suggest that the Li4Ti5O12//LiCo2/3Ni1/6Mn1/6O2 full cell is a potential candidate for battery application due to its excellent cycling performance and improved safety.

Disciplines :

Chemistry

Author, co-author :

Mahmoud, Abdelfattah ; Université de Liège > Département de chimie (sciences) > LCIS - GreenMAT

Saadoune, Ismael

Lippens, Pierre-Emmanuel

Chamas, Mohamad

Hakkou, Rachid

José Manuel, Amarilla

Language :

English

Title :

The design and study of new Li-ion full cells of LiCo2/3Ni1/6Mn1/6O2 positive electrode paired with MnSn2 and Li4Ti5O12 negative electrodes

Publication date :

January 2017

Journal title :

Solid State Ionics

ISSN :

0167-2738

Publisher :

Elsevier Science, Amsterdam, Netherlands

Volume :

300

Pages :

175-181

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 08 February 2017

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