Organometallic-mediated radical polymerization of 'less activated monomers': fundamentals, challenges and opportunities

[en] Access to well-defined polymers made of the so-called ‘Less Activated Monomers’ (LAMs) via controlled radical polymerization has long been a challenge due to the lack of radical stabilizing group on the double bond of these monomers. This Feature Article summarizes substantial progress in the organometallic-mediated radical polymerization (OMRP) of this important class of monomers including vinyl esters, olefins, vinyl chloride, vinyl amides, or ionic-liquid vinyl monomers. It aims to provide a clear and comprehensive account of the fundamentals and challenges in the OMRP of LAMs as well as an overview of the resulting macromolecular engineering opportunities. The input of photochemistry, environmentally friendly solvents or flow reactors in OMRP is also presented. Finally, it emphasizes how some well-defined LAMs-based materials contributed to the development of specific applications notably in the fields of biomedicine or energy.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)
CESAM Complex and Entangled Systems from Atoms to Materials (CESAM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Debuigne, Antoine ; University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; University of Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Organometallic-mediated radical polymerization of 'less activated monomers': fundamentals, challenges and opportunities

Publication date :

21 April 2017

Journal title :

Polymer

ISSN :

0032-3861

eISSN :

1873-2291

Publisher :

Elsevier Science, Oxford, United Kingdom

Volume :

115

Pages :

285-307

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Available on ORBi :

since 31 January 2017

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144 (26 by ULiège)

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