[en] We used tandem ion mobility spectrometry measurements to investigate how the photo-isomerization of a chromophore (a methylpyridinium derivative) is affected by the complexation with a crown ether. A dramatic blue-shift of the photo-isomerization spectrum was observed upon complexation, which could be well reproduced by ab initio calculations. Our results support that the observed changes in the photo-physical properties of the chromophore originate from the charge-solvation of its pyridinium moiety by the host cage.
Disciplines :
Chemistry
Author, co-author :
Czerwinska, Izabella; Université de Liège > Département de chimie (Sciences) > Laboratoire de spectrométrie de masse
Kulesza, Alexander; Université Claude Bernard - Lyon 1 - UCLB > Institut Lumière Matière
Choi, Changmin; Université Claude Bernard - Lyon 1 - UCLB > Institut Lumière Matière
Chirot, Fabien; Université Claude Bernard - Lyon 1 - UCLB > Institut des Sciences Analytiques
Simon, Anne-Laure; Université Claude Bernard - Lyon 1 - UCLB > Institut Lumière Matière
Far, Johann ; Université de Liège > Département de chimie (sciences) > Center for Analytical Research and Technology (CART)
Kune, Christopher ; Université de Liège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.)
De Pauw, Edwin ; Université de Liège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.)
Dugourd, Philippe; Université Claude Bernard - Lyon 1 - UCLB > Institut Lumière Matière
Language :
English
Title :
Supramolecular influence on cis–trans isomerization probed by ion mobility spectrometry
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