[en] An increasingly known application of nanomaterials in the construction industry is related to the photoactivity ability of semiconductors, where nano-anatase TiO2 is perhaps the most well-known photocatalytic semiconductor and one which possesses a strong oxidizing capability. To analyze the photo-efficiency of four TiO2 coatings and the effect of SiO2 interlayer on the mechanic and photocatalytic activity in Rhodamine B (RhB) and NOx photodegradation, two photocatalytic cement series have been prepared. First, cement mortar was coated with three commercial TiO2 suspensions (GG1, GC7 and CG13) and a home-made titania sol-gel (TEA), and secondly an insertion of a SiO2 layer was applied on cement surface before spraying the TiO2 layer.All studied TiO2-cements exhibited a significant RhB and NOx photodegradation, arising almost total RhB molar conversions, and upper 53% for NOx photo-oxidation respectively. Nevertheless, although SiO2 layer deposited in between mortar and TiO2-cement did not stabilize the commercial TiO2 coatings, a good adhesion was observed when silica was applied joint to the home-made titania gel (TEA), probably as a consequence of the interactions encountered between SiO2 and TiO2 gels. CG7-Si-Cem exhibited high rate at shorter irradiation times, but TEA-Cem and TEA-Si-Cem can be considered as very interesting and potential photocatalytic mortars due to useful mechanical properties, with a very good coatings adhesion that provides promising outdoor use, and good photo-efficiencies in RhB and NOx photo-oxidation.
Disciplines :
Materials science & engineering
Author, co-author :
Mendoza Gallego, Carlos ; Spanish National Research Council > Instituto de Catálisis y Petroleoquímica - ICP-CSIC
Valle, Alberto; Spanish National Research Council > Instituto de Catálisis y Petroleoquímica - ICP-CSIC
Castellote, Marta; Spanish National Research Council > Instituto de Ciencias de la Construcción Eduardo Torroja - CSIC
Bahamonde, Ana; Spanish National Research Council > Instituto de Catálisis y Petroleoquímica - ICP-CSIC
Faraldos, Marisol; Spanish National Research Council > Instituto de Catálisis y Petroleoquímica - ICP-CSIC
Language :
English
Title :
TiO2 and TiO2-SiO2 coated cement: Comparison of mechanic and photocatalytic properties
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