[en] Cobalt-Mediated Radical Polymerization (CMRP) is one of the most efficient techniques to form sequenced copolymers between monomers of very different reactivities(e.g. vinyl acetate and acrylonitrile). CMRP is used here to synthesize nanogels of vinylic monomers (either vinyl acetate or ionic liquid monomers) using different concentrations of cross-linking agent (divinyl adipate, or divinyl imidazolium). The aim is to determine the difference in structure of the nanogels, in order to use them for the preparation of star-like and/or core-shell structures.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Weiss-Maurin, Mathilde ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Taton, Daniel; University of Bordeaux, Laboratoire de Chimie des Polymères Organiques (LCPO), France
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Nanogels synthesis by cobalt-mediated radical polymerization (CMRP) in the presence of divinylic cross-linking agents
Publication date :
19 May 2014
Event name :
Belgian Polymer Group (BPG) Annual Meeting
Event place :
Ghent, Belgium
Event date :
19/05/2014 - 20/05/2014
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique The International Doctoral School IDS-Funmat
Commentary :
This poster was presented by Mathilde Weiss-Maurin
