[en] iving/controlled polymerization methods have enabled the synthesis of numerous (co)polymers with defined compositions and architectures. However, the precision design of poly(vinylamine)-based copolymers remains challenging despite their extensive use in various fields of applications and the clear benefits to finely tune their properties. Here, we report on a two-step strategy for the synthesis of tailor-made poly(vinylamine) derivatives through the organometallic- mediated radical (co)polymerization (OMRP) of N-vinyl- acetamide and/or N-methylvinylacetamide followed by acid hydrolysis of the acetamide groups. A series of well-defined homopolymers as well as statistical and block copolymers with pendant primary and/or secondary amines having controlled molar masses, compositions, and low dispersities were produced accordingly. The reactivity ratios of the comonomers as well as the composition drift along the chain were determined in order to have a precise idea of the polymer structures. These advances represent a significant step toward an efficient platform for synthesis of this important class of amino group-containing (co)polymers.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM) The Unit research: Complex and Entangled Systems from Atoms to Materials (CESAM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Dréan, Mathilde ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Guégan, Philippe; Sorbonne University, University Paris 6, CNRS, Institut Parisien de Chimie Moléculaire, Team “Chimie des Polymères” (LCP), Paris, France
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Rieger, Jutta ; Sorbonne University, University Paris 6, CNRS, Institut Parisien de Chimie Moléculaire, Team “Chimie des Polymères” (LCP), Paris, France
Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Controlled synthesis of poly(vinylamine)-based copolymers by organometallic-mediated radical polymerization
Publication date :
28 June 2016
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
American Chemical Society, Washington, United States - District of Columbia
Volume :
49
Issue :
13
Pages :
4817-4827
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique The International Doctoral School IDS-Funmat
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