[en] Formic acid (HCOOH) is one of the most abundant volatile organic compounds in the atmosphere. It is a major contributor to rain acidity in remote areas. There are, however, large uncertainties on the sources and sinks of HCOOH and therefore HCOOH is misrepresented by global chemistry-transport models. This work presents global distributions from 2008 to 2014 as derived from the measurements of the Infrared Atmospheric Sounding Interferometer (IASI), based on conversion factors between brightness temperature differences and representative retrieved total columns over seven regions: Northern Africa, southern Africa, Amazonia, Atlantic, Australia, Pacific, and Russia. The dependence of the measured HCOOH signal on the thermal contrast is taken into account in the conversion method. This conversion presents errors lower than 20 % for total columns ranging between 0.5 and 1 × 1016 molec/cm2 but reaches higher values, up to 78 %, for columns that are lower than 0.3 × 1016 molec/cm2. Signatures from biomass burning events are highlighted, such as in the Southern Hemisphere and in Russia, as well as biogenic emission sources, e.g., over the eastern USA. A comparison between 2008 and 2014 with ground-based Fourier transform infrared spectroscopy (FTIR) measurements obtained at four locations (Maido and Saint-Denis at La Réunion, Jungfraujoch, and Wollongong) is shown. Although IASI columns are found to correlate well with FTIR data, a large bias (> 100 %) is found over the two sites at La Réunion. A better agreement is found at Wollongong with a negligible bias. The comparison also highlights the difficulty of retrieving total columns from IASI measurements over mountainous regions such as Jungfraujoch. A comparison of the retrieved columns with the global chemistry-transport model IMAGESv2 is also presented, showing good representation of the seasonal and interannual cycles over America, Australia, Asia, and Siberia. A global model underestimation of the distribution and a misrepresentation of the seasonal cycle over India are also found. A small positive trend in the IASI columns is observed over Australia, Amazonia, and India over the 2008–2014 period (from 0.7 to 1.5 %/year), while a decrease of ∼ 0.8 %/year is measured over Siberia.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Pommier, M.
Clerbaux, C.
Coheur, P.-F.
Mahieu, Emmanuel ; Université de Liège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Müller, J.-F.
Paton-Walsh, C.
Stavrakou, T.
Vigouroux, C.
Language :
English
Title :
HCOOH distributions from IASI for 2008-2014: comparison with ground-based FTIR measurements and a global chemistry-transport model
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
Andreae, M. O., Andreae, T. W., Talbot, R. W., and Harriss, R. C.: Formic and acetic acid over the central Amazon region, Brazil. I. Dry season, J. Geophys. Res., 93, 1616-1624, doi:10.1029/JD093iD02p01616, 1988.
Andrews, D. U., Heazlewood, B. R., Maccarone, A. T., Conroy, T., Payne, R. J., Jordan, M. J. T., and Kable, S. H.: Phototautomerization of acetaldehyde to vinyl alcohol: a potential route to tropospheric acids, Science, 337, 1203-1206, 2012.
Bohn, B., Siese, M., and Zetzschn, C.: Kinetics of the OHCC2H2 reaction in the presence of O2, J. Chem. Soc. Faraday T., 92, 1459-1466, 1996.
Cady-Pereira, K. E., Chaliyakunnel, S., Shephard, M. W., Millet, D. B., Luo, M., and Wells, K. C.: HCOOH measurements from space: TES retrieval algorithm and observed global distribution, Atmos. Meas. Tech., 7, 2297-2311, doi:10.5194/amt-7-2297-2014, 2014.
Chaliyakunnel, S., Millet, D. B., Wells, K. C., Cady-Pereira, K. E., and Shephard, M. W.: A Large Underestimate of Formic Acid from Tropical Fires: Constraints from Space-Borne Measurements, Environ. Sci. Technol., 50, 5631-5640, doi:10.1021/acs.est.5b06385, 2016.
Clarisse, L., Coheur, P. F., Prata, A. J., Hurtmans, D., Razavi, A., Phulpin, T., Hadji-Lazaro, J., and Clerbaux, C.: Tracking and quantifying volcanic SO2 with IASI, the September 2007 eruption at Jebel at Tair, Atmos. Chem. Phys., 8, 7723-7734, doi:10.5194/acp-8-7723-2008, 2008.
Clerbaux, C. and Crevoisier, C.: New Directions: Infrared remote sensing of the troposphere from satellite: Less, but better, Atmos. Environ., 72, 24-26, doi:10.1016/j.atmosenv.2013.01.057, 2013.
Clerbaux, C., Boynard, A., Clarisse, L., George, M., Hadji-Lazaro, J., Herbin, H., Hurtmans, D., Pommier, M., Razavi, A., Turquety, S., Wespes, C., and Coheur, P.-F.: Monitoring of atmospheric composition using the thermal infrared IASI/MetOp sounder, Atmos. Chem. Phys., 9, 6041-6054, doi:10.5194/acp-9-6041-2009, 2009.
Clubb, A. E., Jordan, M. J. T., Kable, S. H., and Osborn, D. L.: Phototautomerization of Acetaldehyde to vinyl alcohol: a primary process in UV-irradiated acetaldehyde from 295 to 335 nm, J. Phys. Chem. Lett., 3, 3522-3526, 2012.
CNES (Centre National dEtudes Spatiales) and INSU (Institut National des Sciences de l'Univers): Ether database, available at: http://ether.ipsl.jussieu.fr, last access: 15 July 2016.
Coheur, P. F., Clerbaux, C., and Colin, R.: Spectroscopic measurements of halocarbons and hydrohalocarbons by satellite-borne remote sensors, J. Geophys. Res., 108, 4130, doi:10.1029/2002JD002649, 2003.
Coheur, P.-F., Barret, B., Turquety, S., Hurtmans, D., Hadji-Lazaro, J., and Clerbaux, C.: Retrieval and characterization of ozone vertical profiles from a thermal infrared nadir sounder, J. Geophys. Res., 110, D24303, doi:10.1029/2005JD005845, 2005.
Crevoisier, C., Clerbaux, C., Guidard, V., Phulpin, T., Armante, R., Barret, B., Camy-Peyret, C., Chaboureau, J.-P., Coheur, P.-F., Crépeau, L., Dufour, G., Labonnote, L., Lavanant, L., Hadji-Lazaro, J., Herbin, H., Jacquinet-Husson, N., Payan, S., Péquignot, E., Pierangelo, C., Sellitto, P., and Stubenrauch, C.: Towards IASI-New Generation (IASI-NG): impact of improved spectral resolution and radiometric noise on the retrieval of thermodynamic, chemistry and climate variables, Atmos. Meas. Tech., 7, 4367-4385, doi:10.5194/amt-7-4367-2014, 2014.
González Abad, G., Bernath, P. F., Boone, C. D., McLeod, S. D., Manney, G. L., and Toon, G. C.: Global distribution of upper tropospheric formic acid from the ACE-FTS, Atmos. Chem. Phys., 9, 8039-8047, doi:10.5194/acp-9-8039-2009, 2009.
Goode, J., Yokelson, R., Ward, D., Susott, R., Babbitt, R., Davies, M., and Hao, W.: Measurements of excess O3, CO2, CO, CH4, C2H4, C2H2, HCN, NO, NH3, HCOOH, CH3COOH, HCHO, and CH3OH in 1997 Alaskan biomass burning plumes by airborne Fourier transform infrared spectroscopy (AFTIR), J. Geophys. Res., 105, 22147, doi:10.1029/2000JD900287, 2000.
Graedel, T. and Eisner, T.: Atmospheric formic acid from formicine ants: a preliminary assessment, Tellus B, 40, 335-339, 1988.
Grosjean, D.: Organic acids in southern California air: ambient concentrations, mobile source emissions, in situ formation and removal processes, Environ. Sci. Technol., 23, 1506-1514, 1989.
Grutter, M., Glatthor, N., Stiller, G. P., Fischer, H., Grabowski, U., Höpfner, M., Kellmann, S., Linden, A., and von Clarmann, T.: Global distribution and variability of formic acid as observed by MIPAS-ENVISAT, J. Geophys. Res., 115, D10303, doi:10.1029/2009JD012980, 2010.
Hatakeyama, S., Washida, N., and Akimoto, H.: Rate constants and mechanisms for the reaction of hydroxyl (OD) radicals with acetylene, propyne, and 2-butyne in air at 2972 K, J. Phys. Chem., 6, 173-178, 1986.
Hooghiemstra, P. B., Krol, M. C., van Leeuwen, T. T., van derWerf, G. R., Novelli, P. C., Deeter, M. N., Aben, I., and Röckmann, T.: Interannual variability of carbon monoxide emission estimates over South America from 2006 to 2010, J. Geophys. Res., 117, D15308, doi:10.1029/2012JD017758, 2012.
Jones, B. T., Muller, J. B. A., O'Shea, S. J., Bacak, A., Le Breton, M., Bannan, T. J., Leather, K. E., Murray Booth, A., Illingworth, S., Bower, K., Gallagher, M. W., Allen, G., Dudley Shallcross, E., Bauguitte, S. J.-B., Pyle, J. A., and Percival, C. J.: Airborne measurements of HC(O)OH in the European Arctic: A winter summer comparison, Atmos. Environ., 99, 556-567, doi:10.1016/j.atmosenv.2014.10.030, 2014.
Kawamura, K., Ng, L., and Kaplan, I.: Determination of organic acids (C1-C10) in the atmosphere, motor exhausts, and engine oils, Environ. Sci. Technol., 19, 1082-1086, 1985.
Keene, W. and Galloway, J.: Organic acidity in precipitation of North America, Atmos. Environ., 18, 2491-2497, 1984.
Keene, W. C. and Galloway, J. N.: The biogeochemical cycling of formic and acetic acids through the troposphere: An overview of current understanding, Tellus B, 40, 322-334, 1988.
Kurokawa, J., Ohara, T., Morikawa, T., Hanayama, S., Janssens-Maenhout, G., Fukui, T., Kawashima, K., and Akimoto, H.: Emissions of air pollutants and greenhouse gases over Asian regions during 2000-2008: Regional Emission inventory in ASia (REAS) version 2, Atmos. Chem. Phys., 13, 11019-11058, doi:10.5194/acp-13-11019-2013, 2013.
Lee, A., Goldstein, A. H., Kroll, J. H., Ng, N. L., Varutbangkul, V., Flagan, R. C., and Seinfeld, J. H.: Gas-phase products and secondary aerosol yields from the photooxidation of 16 different terpenes, J. Geophys. Res., 111, D17305, doi:10.1029/2006JD007050, 2006.
Millet, D. B., Baasandorj, M., Farmer, D. K., Thornton, J. A., Baumann, K., Brophy, P., Chaliyakunnel, S., de Gouw, J. A., Graus, M., Hu, L., Koss, A., Lee, B. H., Lopez-Hilfiker, F. D., Neuman, J. A., Paulot, F., Peischl, J., Pollack, I. B., Ryerson, T. B., Warneke, C., Williams, B. J., and Xu, J.: A large and ubiquitous source of atmospheric formic acid, Atmos. Chem. Phys., 15, 6283-6304, doi:10.5194/acp-15-6283-2015, 2015.
Neeb, P., Sauer, F., Horie, O., and Moortgat, G. K.: Formation of hydroxymethyl hydroperoxide and formic acid in alkene ozonolysis in the presence of water vapour, Atmos. Environ., 31, 1417-1423, 1997.
Ngwabie, N. M., Schade, G. W., Custer, T. G., Linke, S., and Hinz, T.: Abundances and flux estimates of volatile organic compounds from a dairy cowshed in Germany, J. Environ. Qual., 37, 565-573, 2008.
Paton-Walsh, C., Jones, N. B., Wilson, S. R., Haverd, V., Meier, A., Griffith, D. W. T., and Rinsland, C. P.: Measurements of trace gas emissions from Australian forest fires and correlations with coincident measurements of aerosol optical depth, J. Geophys. Res.-Atmos., 110, D24305, doi:10.1029/2005JD006202, 2005.
Paulot, F., Wunch, D., Crounse, J. D., Toon, G. C., Millet, D. B., DeCarlo, P. F., Vigouroux, C., Deutscher, N. M., González Abad, G., Notholt, J., Warneke, T., Hannigan, J. W., Warneke, C., de Gouw, J. A., Dunlea, E. J., De Mazière, M., Griffith, D. W. T., Bernath, P., Jimenez, J. L., and Wennberg, P. O.: Importance of secondary sources in the atmospheric budgets of formic and acetic acids, Atmos. Chem. Phys., 11, 1989-2013, doi:10.5194/acp-11-1989-2011, 2011.
Razavi, A., Karagulian, F., Clarisse, L., Hurtmans, D., Coheur, P. F., Clerbaux, C., Müller, J. F., and Stavrakou, T.: Global distributions of methanol and formic acid retrieved for the first time from the IASI/MetOp thermal infrared sounder, Atmos. Chem. Phys., 11, 857-872, doi:10.5194/acp-11-857-2011, 2011.
R'Honi, Y., Clarisse, L., Clerbaux, C., Hurtmans, D., Duflot, V., Turquety, S., Ngadi, Y., and Coheur, P.-F.: Exceptional emissions of NH3 and HCOOH in the 2010 Russian wildfires, Atmos. Chem. Phys., 13, 4171-4181, doi:10.5194/acp-13-4171-2013, 2013.
Rodgers, C. D.: Inverse methods for atmospheric sounding: theory and practice, Ser. Atmos. Ocean. Planet. Phys. 2, World Sci., Hackensack, NJ, USA, 2000.
Rothman, L. S., Gordon, I. E., Barbe, A., Benner, D. C., Bernath, P. F., Birk, M., Boudon, V., Brown, L. R., Campargue, A., Champion, J., Chance, K., Coudert, L. H., Dana, V., Devi, V. M., Fally, S., Flaud, J., Gamache, R. R., Goldman, A., Jacquemart, D., Kleiner, I., Lacome, N., Lafferty, W. J., Mandin, J., Massie, S. T., Mikhailenko, S. N., Miller, C. E., Moazzen-Ahmadi, N., Naumenko, O. V., Nikitin, A. V., Orphal, J., Perevalov, V. I., Perrin, A., Predoi-Cross, A., Rinsland, C. P., Rotger, M., Simeckova, M., Smith, M. A. H., Sung, K., Tashkun, S. A., Tennyson, J., Toth, R. A., Vandaele, A. C., and Vander Auwera, J.: The HITRAN 2008 molecular spectroscopic database, J. Quant. Spectrosc. Ra., 110, 533-572, doi:10.1016/j.jqsrt.2009.02.013, 2009.
Sanhueza, E. and Andreae, M.: Emission of formic and acetic acids from tropical savanna soils, Geophys. Res. Lett., 18, 1707-1710, 1991.
Sanhueza, E., Figueroa, L., and Santana, M.: Atmospheric formic and acetic acids in Venezuela, Atmos. Environ., 30, 1861-1873, 1996.
Schultz, M. G., Backman, L., Balkanski, Y., Bjoerndalsaeter, S., Brand, R., Burrows, J. P., Dalsoeren, S., de Vasconcelos, M., Grodtmann, B., Hauglustaine, D. A., Heil, A., Hoelzemann, J. J., Isaksen, I. S. A., Kaurola, J., Knorr, W., Ladstaetter-Weißenmayer, A., Mota, B., Oom, D., Pacyna, J., Panasiuk, D., Pereira, J. M. C., Pulles, T., Pyle, J., Rast, S., Richter, A., Savage, N., Schnadt, C., Schulz, M., Spessa, A., Staehelin, J., Sundet, J. K., Szopa, S., Thonicke, K., van het Bolscher, M., van Noije, T., van Velthoven, P., Vik, A. F., and Wittrock, F.: REanalysis of the TROpospheric chemical composition over the past 40 years (RETRO): A long-term global modeling study of tropospheric chemistry, Jülich/Hamburg, Germany, 48/2007 report on Earth System Science of the Max Planck Institute for Meteorology, Hamburg, ISSN 1614-1199, available at: http://retro-archive.iek. fz-juelich.de/data/documents/ (last access: 13 July 2016), 2007.
Sindelarova, K., Granier, C., Bouarar, I., Guenther, A., Tilmes, S., Stavrakou, T., Müller, J.-F., Kuhn, U., Stefani, P., and Knorr, W.: Global data set of biogenic VOC emissions calculated by the MEGAN model over the last 30 years, Atmos. Chem. Phys., 14, 9317-9341, doi:10.5194/acp-14-9317-2014, 2014.
Stavrakou, T., Guenther, A., Razavi, A., Clarisse, L., Clerbaux, C., Coheur, P.-F., Hurtmans, D., Karagulian, F., De Mazière, M., Vigouroux, C., Amelynck, C., Schoon, N., Laffineur, Q., Heinesch, B., Aubinet, M., Rinsland, C., and Müller, J.-F.: First space-based derivation of the global atmospheric methanol emission fluxes, Atmos. Chem. Phys., 11, 4873-4898, doi:10.5194/acp-11-4873-2011, 2011.
Stavrakou, T., Müller, J-F., Peeters, J., Razavi, A., Clarisse, L., Clerbaux, C., Coheur, P.-F., Hurtmans, D., and De Mazière, M.: Satellite evidence for a large source of formic acid from boreal and tropical forests, Nat. Geosci., 5, 26-30, doi:10.1038/ngeo1354, 2012.
Stavrakou, T., Müller, J.-F., Bauwens, M., De Smedt, I., Van Roozendael, M., Guenther, A., Wild, M., and Xia, X.: Isoprene emissions over Asia 1979-2012: impact of climate and land-use changes, Atmos. Chem. Phys., 14, 4587-4605, doi:10.5194/acp-14-4587-2014, 2014.
Talbot, R. W., Dibb, J. E., Lefer, B. L., Scheuer, E. M., Bradshaw, J. D., Sandholm, S. T., Smyth, S., Blake, D. R., Blake, N. J., Sachse, G. W., Collins, J. E., and Gregory, G. L.: Large-scale distributions of tropospheric nitric, formic, and acetic acids over the western Pacific basin during wintertime, J. Geophys. Res., 102, 28303-28313, doi:10.1029/96JD02975, 1997a.
Talbot, R. W., Dibb, J. E., Lefer, B. L., Bradshaw, J. D., Sandholm, S. T., Blake, D. R., Blake, N. J., Sachse, G. W., Collins, J. E., Heikes, B. G., Merrill, J. T., Gregory, G. L., Anderson, B. E., Singh, H. B., Thornton, D. C., Bandy, A. R., and Pueschel, R. F.: Chemical characteristics of continental outflow from Asia to the troposphere over the western Pacific Ocean during February-March 1994: Results from PEM-West B, J. Geophys. Res., 102, 28255-28274, doi:10.1029/96JD02340, 1997b.
Talbot, R. W., Dibb, J. E., Scheuer, E. M., Blake, D. R., Blake, N. J., Gregory, G. L., Sachse, G. W., Bradshaw, J. D., Sandholm, S. T., and Singh, H. B.: Influence of biomass combustion emissions on the distribution of acidic trace gases over the Southern Pacific basin during austral springtime, J. Geophys. Res., 104, 5623-5634, 1999.
Van Damme, M., Clarisse, L., Heald, C. L., Hurtmans, D., Ngadi, Y., Clerbaux, C., Dolman, A. J., Erisman, J. W., and Coheur, P. F.: Global distributions, time series and error characterization of atmospheric ammonia (NH3) from IASI satellite observations, Atmos. Chem. Phys., 14, 2905-2922, doi:10.5194/acp-14-2905-2014, 2014.
Vander Auwera, J., Didriche, K., Perrin, A., and Keller, F.: Absolute line intensities for formic acid and dissociation constant of the dimer, J. Chem. Phys., 126, 124311, doi:10.1063/1.2712439, 2007.
van derWerf, G. R., Randerson, J. T., Giglio, L., Collatz, G. J., Mu, M., Kasibhatla, P. S., Morton, D. C., DeFries, R. S., Jin, Y., and van Leeuwen, T. T.: Global fire emissions and the contribution of deforestation, savanna, forest, agricultural, and peat fires (1997-2009), Atmos. Chem. Phys., 10, 11707-11735, doi:10.5194/acp-10-11707-2010, 2010.
Vigouroux, C., Stavrakou, T., Whaley, C., Dils, B., Duflot, V., Hermans, C., Kumps, N., Metzger, J.-M., Scolas, F., Vanhaelewyn, G., Müller, J.-F., Jones, D. B. A., Li, Q., and De Mazière, M.: FTIR time-series of biomass burning products (HCN, C2H6, C2H2, CH3OH, and HCOOH) at Reunion Island (21 S, 55 E) and comparisons with model data, Atmos. Chem. Phys., 12, 10367-10385, doi:10.5194/acp-12-10367-2012, 2012.
Wallace, J. M. and Hobbs, P. V.: Atmospheric Science: An Introductory Survey, ISBN-13: 978-0127329512, Academic Press, New York, USA, 1977.
Whitburn, S., Van Damme, M., Kaiser, J. W., van der Werf, G. R., Turquety, S., Hurtmans, D., Clarisse, L., Clerbaux, C., and Coheur, P.-F.: Ammonia emissions in tropical biomass burning regions: Comparison between satellite-derived emissions and bottom-up fire inventories, Atmos. Environ, 121, 42-54, doi:10.1016/j.atmosenv.2015.03.015, 2015.
Zander, R., Duchatelet, P., Mahieu, E., Demoulin, P., Roland, G., Servais, C., Auwera, J. V., Perrin, A., Rinsland, C. P., and Crutzen, P. J.: Formic acid above the Jungfraujoch during 1985-2007: observed variability, seasonality, but no long-term background evolution, Atmos. Chem. Phys., 10, 10047-10065, doi:10.5194/acp-10-10047-2010, 2010.
Similar publications
Sorry the service is unavailable at the moment. Please try again later.
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.