Gradient foaming of polycarbonate/carbon nanotube based nanocomposites with supercritical carbon dioxide and their EMI shielding performances

Monnereau, Laure; Urbanczyk, Laetitia; Thomassin, Jean-Michel; Pardoen, Thomas; Bailly, Christian; Huynen, Isabelle; Jérôme, Christine; Detrembleur, Christophe

doi:10.1016/j.polymer.2014.11.063

Article (Scientific journals)

Gradient foaming of polycarbonate/carbon nanotube based nanocomposites with supercritical carbon dioxide and their EMI shielding performances

Monnereau, Laure; Urbanczyk, Laetitia; Thomassin, Jean-Michel et al.

2015 • In Polymer, 59, p. 117-123

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/190397

DOI
10.1016/j.polymer.2014.11.063

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Keywords :

supercritical carbon dioxide; nanocomposite; foam; electromagnetic interferences (EMI) shielding material

Abstract :

[en] Sorption and diffusion of supercritical carbon dioxide (scCO2) into polycarbonate (PC) nanocomposites loaded with 0, 1 and 2 wt% of multi-walled carbon nanotubes (MWNTs) have been investigated. After determination of the saturation equilibrium, the samples have been saturated with scCO2 to ensure a partial foaming with a density gradient from the surface to the center of the samples and the morphology of the porous materials has been analysed by SEM. The gradient materials were very advantageous for EMI shielding since the foamed structure at the surface had low dielectric constant and limited the reflection of the EM signal while the presence of highly conductive solid in the middle ensured a high absorption of the electromagnetic radiation.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Monnereau, Laure; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Urbanczyk, Laetitia; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Thomassin, Jean-Michel ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Pardoen, Thomas; Université catholique de Louvain (UCL), Research Center in Architectured and Composite Materials (ARCOMAT)

Bailly, Christian; Université catholique de Louvain (UCL), Research Center in Architectured and Composite Materials (ARCOMAT)

Huynen, Isabelle; Université catholique de Louvain (UCL), Research Center in Architectured and Composite Materials (ARCOMAT)

Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Gradient foaming of polycarbonate/carbon nanotube based nanocomposites with supercritical carbon dioxide and their EMI shielding performances

Publication date :

24 February 2015

Journal title :

Polymer

ISSN :

0032-3861

eISSN :

1873-2291

Publisher :

Elsevier Science, Oxford, United Kingdom

Volume :

Pages :

117-123

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
The "Région Wallonne" in the frame of the MULTIMASEC program

Available on ORBi :

since 06 January 2016

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