Mass Spectrometry; Dissociative Electron Attachment; Electron Impact; Diatomic Molecules: NO, O2
Abstract :
[en] The DA processes of O- ions in NO and O2 are investigated using a 60° sector field mass spectrometer. In NO O- appears at (7.43+/-0.2) eV and the analysis of the DA curve indicates the probable existence of two other processes at 8.1 eV and 9.0 eV. In O2 only one process is observed at (3.45+/-0.3) eV. For both molecules an attempt is made to establish the shape of the potential energy curve of the electronic states of the transient negative molecular species involved.
Research Center/Unit :
Laboratoire de Dynamique Moléculaire
Disciplines :
Chemistry
Author, co-author :
Locht, Robert ; Université de Liège - ULiège > Departement de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Momigny, Jacques; Université de Liège - ULiège > Faculté des Sciences > Laboratoire des Etats Ionisés
Language :
English
Title :
Mass Spectrometric Study of Dissociative Attachment in Diatomic Molecules. II. NO and O2.
Alternative titles :
[fr] Etude de l'attachement électronique dissociatif dans les molécules biatomiques par spectrométrie de masse: II. NO et O2.
Publication date :
1970
Journal title :
International Journal of Mass Spectrometry and Ion Physics
ISSN :
0020-7381
eISSN :
1873-3034
Publisher :
Elsevier, Amsterdam, Netherlands
Volume :
4
Pages :
379-391
Peer reviewed :
Peer reviewed
Funders :
FRFC - Fonds de la Recherche Fondamentale Collective F.R.S.-FNRS - Fonds de la Recherche Scientifique
Commentary :
- Printed version of reprint available on request
- Version imprimée du tiré-à-part disponible sur demande
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Bibliography
Locht, Momigny Int. J. Mass Spectrom. Ion Phys. 1969, 2:425.
Dorman (1968) Negative Fragment Ions from Resonance Capture Processes. The Journal of Chemical Physics 44:3856.
Chantry Phys. Rev. 1968, 172:125.
Frost, McDowell J. Chem. Phys. 1958, 29:1424.
Hierl, Franklin J. Chem. Phys. 1967, 47:3154.
Rapp, Briglia J. Chem. Phys. 1965, 43:1480.
Dibeler, Walker (1967) Mass-Spectrometric Study of Photoionization VI O_2, CO_2 COS, and CS_2. Journal of the Optical Society of America 57:1007.
Chantry, Schulz Phys. Rev. 1967, 156:134.
.
Mariott, Craggs Applied Mass Spectrometry , Inst. of Petroleum, London; 1956, 173.
Frost, McDowell J. Am. Chem. Soc. 1958, 80:6183.
Craggs, Thorburn, Tozer Proc. Phys. Soc. 1957, 240 A:473.
Schulz Phys. Rev. 1962, 128:178.
Randolph, Geballe Thesis, University of Washington; 1958.
Brion, Thomas Int. J. Mass Spectrom. Ion Phys. 1968, 1:25.
Herzberg Spectra of Diatomic Molecules, Van Nostrand, New York; 1950.
Smith, Branscomb (1955) Atomic negative-ion-photodetachment cross-section and affinity measurements. Journal of Research of the National Bureau of Standards 55:165.
Moore Atomic Energy Levels, Natl. Bur. Std. (U.S.), Circ. 1949, 1:467.
O'Malley Phys. Rev. 1967, 155:59.
Gilmore (1969) Potential energy curves for N2, NO, O2 and corresponding ions. Journal of Quantitative Spectroscopy and Radiative Transfer 5:369.
Lefebvre-Brion, Moser J. Chem. Phys. 1966, 44:2951.
O'Malley Phys. Rev. 1966, 150:14.
McNeil, Thynne (1969) The deconvolution of negative ion data. International Journal of Mass Spectrometry and Ion Physics 3:35.
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