Reference : Controlled synthesis of ethylene-vinyl acetate based copolymers by organometallic med...
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http://hdl.handle.net/2268/181464
Controlled synthesis of ethylene-vinyl acetate based copolymers by organometallic mediated radical polymerization
English
Demarteau, Jérémy [University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)]
Kermagoret, Anthony [University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)]
Jérôme, Christine mailto [University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)]
Detrembleur, Christophe mailto [University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)]
Debuigne, Antoine mailto [University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)]
1-May-2015
Controlled Radical Polymerization: Materials
Matyjaszewski, Krzysztof
Sumerlin, Brent S.
Tsarevsky, Nicolay V.
Chiefari, John
American Chemical Society
ACS Symposium Series
47-61
Yes
[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP)
[en] The controlled radical copolymerization of ethylene (E) and vinyl acetate (VAc) is further investigated by organometallic- mediated radical polymerization (OMRP) using Co(acac)2 as controlling agent at ethylene pressure up to 100 bar. The effect of ethylene pressure on kinetics, level of control and copolymer composition, is discussed. Ethylene-Vinyl Acetate copolymers (EVAs) with low dispersities and ethylene content reaching 57 mol% are notably reported. This work also successfully addresses the precision design of EVA-containing block copolymers, i.e. PVAc-block-EVA. In this case, the order of the synthesis of the blocks is a key parameter. The “PVAc-first” strategy is by far more practical and efficient.
Center for Education and Research on Macromolecules (CERM)
Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA ; The University of Liège in the frame of the "Fonds Spéciaux pour la Recherche"
Researchers
http://hdl.handle.net/2268/181464
10.1021/bk-2015-1188.ch004

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