Direct route to well-defined poly(ionic liquid)s by controlled radical polymerization in water

Cordella, Daniela; Kermagoret, Anthony; Debuigne, Antoine; Riva, Raphaël; German, Ian; Isik, Mehmet; Jérôme, Christine; Meccereyes, David; Taton, Daniel; Detrembleur, Christophe

doi:10.1021/mz500721r

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Article (Scientific journals)

Direct route to well-defined poly(ionic liquid)s by controlled radical polymerization in water

Cordella, Daniela; Kermagoret, Anthony; Debuigne, Antoine et al.

2014 • In ACS Macro Letters, 3, p. 1276-1280

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/174743

DOI
10.1021/mz500721r

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); ionic liquid

Abstract :

[en] The precision synthesis of poly(ionic liquid)s (PILs) in water is achieved for the first time by the cobalt-mediated radical polymerization (CMRP) of N-vinyl-3-alkylimidazolium-type monomers following two distinct protocols. The first involves the CMRP of various 1-vinyl-3-alkylimidazolium bromides conducted in water in the presence of an alkyl–cobalt(III) complex acting as a monocomponent initiator and mediating agent. Excellent control over molar mass and dispersity is achieved at 30 °C. Polymerizations are complete in a few hours, and PIL chain-end fidelity is demonstrated up to high monomer conversions. The second route uses the commercially available bis(acetylacetonato)cobalt(II) (Co(acac)2) in conjunction with a simple hydroperoxide initiator (tert-butyl hydroperoxide) at 30, 40, and 50 °C in water, facilitating the scaling-up of the technology. Both routes prove robust and straightforward, opening new perspectives onto the tailored synthesis of PILs under mild experimental conditions in water.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Cordella, Daniela ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Kermagoret, Anthony ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Riva, Raphaël ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

German, Ian ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Isik, Mehmet; University of the Basque Country, Institute for Polymer Materials (POLYMAT), Spain

Jérôme, Christine ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie des macromolécules et des matériaux organiques (CERM)

Meccereyes, David; University of the Basque Country, Institute for Polymer Materials (POLYMAT), Spain

Taton, Daniel; University of Bordeaux, Laboratoire de Chimie des Polymères Organiques (LCPO), France

Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Direct route to well-defined poly(ionic liquid)s by controlled radical polymerization in water

Publication date :

05 December 2014

Journal title :

ACS Macro Letters

eISSN :

2161-1653

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Pages :

1276-1280

Peer reviewed :

Peer Reviewed verified by ORBi

European Projects :

FP7 - 256599 - RENAISSANCE - The Renaissance Project: Towards a strategic orientation and associated toolkit to support global UCD that is appropriate and accountable to local culture

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
CE - Commission Européenne

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