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Electrochemically synthesized polypyrrole nanotubules : effects of different experimental conditions
Demoustier-Champagne, Sophie; Ferain, Etienne; Jérôme, Christine et al.
1998In European Polymer Journal, 34 (12), p. 1767-1774
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Keywords :
electropolymerization; conjugated polymer
Abstract :
[en] Nanotubules of polypyrrole (PPy) were electrochemically synthesized using the pores of nanoporous polycarbonate (PC) particle track-etched membranes (PTM) as templates. The influence of some conditions of electrosynthesis (electrochemical method, monomer concentration, electrolyte concentration and nature) on the kinetics of pyrrole electropolymerization and on the morphology of the obtained nanomaterials has been investigated. In particular, the empirical kinetics of the electrochemical generation of polypyrrole-perchlorate (PPy-ClO4) from aqueous solution, at 0.8 V (vs SCE) was followed by electrical charges measurement. The orders with respect to pyrrole and LiClO4 are 0.34 and 0.70 respectively. The electrogeneration of polypyrrole-polystyrenesulfonate (PPy-PSS) was also followed and shows that an increase of the electrolyte concentration increases the polymerization rate at constant potential. Finally, the morphology of PPy nanotubules doped with LiClO4 and NaPSS has been studied by high resolution emission SEM and by TEM.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Demoustier-Champagne, Sophie;  Université catholique de Louvain (UCL) > Unité de Physique et de Chimie des Hauts Polymères
Ferain, Etienne;  Université catholique de Louvain (UCL) > Unité de Physique et de Chimie des Hauts Polymères
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Legras, Roger;  Université catholique de Louvain (UCL) > Unité de Physique et de Chimie des Hauts Polymères
Language :
English
Title :
Electrochemically synthesized polypyrrole nanotubules : effects of different experimental conditions
Publication date :
December 1998
Journal title :
European Polymer Journal
ISSN :
0014-3057
eISSN :
1873-1945
Publisher :
Pergamon (Elsevier)
Volume :
34
Issue :
12
Pages :
1767-1774
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
Commentary :
The authors acknowledge European Polymer Journal (Elsevier) for allowing them to archive this paper.
Available on ORBi :
since 24 July 2009

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