Addition reaction catalysts (regioselective prepn. of hexenyl benzoate via microwave-assisted ruthenium-catalyzed addn. of benzoic acid to hexyne); Addition reaction; Synthesis
Abstract :
[en] 1-Hexen-2-yl 4-acetoxybenzoate was regioselectively prepd. via microwave-assisted ruthenium-catalyzed addn. of 4-acetoxybenzoic acid to 1-hexyne. Species of catalysts, reaction time and temp. play roles in the reaction respect to yields and selectivity, therefore were examd. Microwave effect was obsd. and preferred to the generation of the Markovnikov-type product compared to traditional heating.
Disciplines :
Chemistry
Author, co-author :
Nicks, Francois ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Libert, Lionel ; Université de Liège - ULiège > Centre de recherches du cyclotron
Delaude, Lionel ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Language :
English
Title :
Microwave-assisted synthesis of vinyl esters through ruthenium-catalyzed addition of carboxylic acids to alkynes
Publication date :
2008
Audience :
International
Journal title :
Polymer Preprints
ISSN :
0032-3934
Publisher :
American Chemical Society, Washington, United States - District of Columbia
