Thiophene derivatives with donor–π–acceptor structures for enhanced light-absorption properties and efficient cationic polymerization upon green-light irradiation
[en] Positively charged thermoresponsive nanogels (NGs) are easily synthesized by precipitation polymerization of N-isopropylacrylamide and 2-dimethyl(aminoethyl)methacrylate crosslinked with dendritic polyglycerol. The NGs are characterized in terms of size, thermoresponsive properties, and Z potential. Their potential applications as drug delivery carriers are evaluated by the encapsulation and release of different anticancer drugs. As model drugs, doxorubicin and methotrexate are studied.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Telitel, Sofia; Institut de Science des Matériaux de Mulhouse, France
Ouhib, Farid ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Fouassier, Jean-Pierre; Institut de Science des Matériaux de Mulhouse, France
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Lalevée, Jacques; Institut de Science des Matériaux de Mulhouse, France
Language :
English
Title :
Thiophene derivatives with donor–π–acceptor structures for enhanced light-absorption properties and efficient cationic polymerization upon green-light irradiation
Publication date :
August 2014
Journal title :
Macromolecular Chemistry and Physics
ISSN :
1022-1352
eISSN :
1521-3935
Publisher :
Wiley-VCH, Weinheim, Germany
Volume :
215
Issue :
16
Pages :
1514-1524
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique The "Région wallonne" and the "European Commission in the frame of the INTERREG program ORGANEXT IUF - Institut Universitaire de France
J. P. Fouassier, J. Lalevée, Photoinitiators for Polymer Synthesis: Scope, Reactivity and Efficiency, Wiley-VCH, Weinheim, Germany 2012.
M. A. Tehfe, J. Lalevée, D. Gigmes, J. P. Fouassier, Macromolecules 2010, 43, 1364.
J. P. Fouassier, J. Lalevée, Adv. Chem., RSC 2012, 2, 2621.
M. A. Tehfe, J. Lalevée, S. Telitel, E. Contal, F. Dumur, D. Gigmes, D. Bertin, M. Nechab, M. Bertrand, F. Morlet Savary, B. Graff, J. P. Fouassier, Macromolecules 2012, 45, 4454.
a) J. V. Crivello, J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 3820
b) M. A. Tehfe, J. Lalevée, F. Morlet Savary, B. Graff, N. Blanchard, J. P. Fouassier, ACS Macro Lett. 2012, 1, 198.
A. Marzena Szymczak, R. Podsiadły, K. Podemska, J. Sokołowska, Color. Technol. 2012, 128, 378.
a) B. Aydogan, Y. Yagci, L. Toppare, S. Jockusch, N. J. Turro, Macromolecules 2012, 45, 7829
b) B. Aydogan, Y. Y. Durmaz, M. U. Kahveci, M. Uygun, M. A. Tasdelen, Y. Yagci, Macromol. Symp. 2011, 308, 25
c) B. Aydogan, G. E. Gunbas, A. Durmus, L. Toppare, Y. Yagci, Macromolecules 2010, 43, 101
d) U. Bulut, G. E. Gunbas, L. Toppare, J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 209
e) U. Bulut, A. Balan, C. Caliskan, J. Polym. Sci., Part A: Polym. Chem. 2011, 49, 729
f) Y. Yagci, S. Jockusch, N. J. Turro, Macromolecules 2007, 40, 4481.
J. Lalevée, M. A. Tehfe, D. Gigmes, N. Blanchard, J. P. Fouassier, Macromolecules 2010, 43, 6608.
a) G. Ayilmaz, B. Iskin, F. Yilmaz, Y. Yagci, ACS Macro Lett. 2012, 1, 1212
b) M. A. Tehfe, J. Lalevée, F. Dumur, A. Zein-Fakih, D. Gigmes, F. Morlet Savary, J. P. Fouassier, Polymer 2012, 53, 4947.
S. Telitel, J. Lalevee, N. Blanchard, T. Kavalli, M. A. Tehfe, F. Morlet Savary, B. Graff, J. P. Fouassier, Macromolecules 2012, 45, 6864.
M. A. Tehfe, J. Lalevée, S. Telitel, J. Sun, J. Zhao, F. Morlet Savary, B. Graff, J. P. Fouassier, Polymer 2012, 53, 2803.
M. A. Tehfe, B. Graff, F. Morlet Savary, J. P. Fouassier, J. Zhao, J. Lalevée, Macromol. Chem. Phys. 2012, 213, 2282.
M. Degirmenci, A. Onen, Y. Yagci, S. P. Pappas, Polym. Bull. 2001, 46, 443.
a) J. Lalevée, M. A. Tehfe, A. Zein-Fakih, B. Ball, S. Telitel, F. Morlet Savary, B. Graff, J. P. Fouassier, ACS Macro Lett. 2012, 1, 802
b) S. M. Linden, D. C. Neckers, J. Am. Chem. Soc. 1988, 110, 1257
c) M. Kawabata, Y. Takimoto, J. Photopolym. Sci. Technol. 1990, 3, 147.
J. Lalevee, N. Blanchard, M. A. Tehfe, M. Peter, F. Morlet Savary, J. P. Fouassier, Polym. Chem. 2011, 2, 1986.
M. A. Tehfe, J. Lalevée, F. Morlet Savary, B. Graff, N. Blanchard, J. P. Fouassier, Macromolecules 2012, 45, 1746.
J. Lalevée, M. A. Tehfe, F. Morlet Savary, J. P. Fouassier, Polym. Chem. 2012, 3, 1899.
K. C. Anyaogu, X. Cai, D. C. Neckers, Macromolecules 2008, 41, 9000.
a) J. Roncali, Chem. Rev. 1997, 97, 173
b) H. A. M. van Mullekom, J. A. J. M. Vekemans, E. E. Havinga, E. W. Meijer, Mater. Sci. Eng. R 2001, 32, 1
c) F. Wudl, M. Kobayashi, A. J. Heeger, J. Org. Chem. 1984, 49, 3382
d) C.-Q. Ma, E. Mena-Osteritz, M. Wunderlin, G. Schulz, P. Bäuerle, Chem. Eur. J. 2012, 18, 12880
e) C. A. Thomas, A. Zong, K. A. Abboud, P. J. Steel, J. R. Reynolds, J. Am. Chem. Soc. 2004, 126, 16440
f) T. Maugard, E. Enaud, P. Choisy, M. D. Legoy, Phytochemistry 2001, 58, 897
g) J. K. Stille, Angew. Chem., Int. Ed. 1986, 25, 508.
a) F. Castellanos, J. P. Fouassier, D. Priou, A. Cavezzan, (Rhone Poulenc), US Pat. 5668192, 1997
b) F. Castellanos, J. P. Fouassier, C. Priou, J. Cavezzan, J. Appl. Polym. Sci. 1996, 60, 705.
a) J. Lalevée, N. Blanchard, M. A. Tehfe, F. Morlet-Savary, J. P. Fouassier, Macromolecules 2010, 43, 10191
b) J. Lalevée, N. Blanchard, M. A. Tehfe, M. Peter, F. Morlet-Savary, J. P. Fouassier, Macromol. Rapid Commun. 2011, 32, 917
c) J. Lalevée, N. Blanchard, M. A. Tehfe, M. Peter, F. Morlet-Savary, J. P. Fouassier, Polym. Bull. 2011, 68, 341.
D. Rehm, A. Weller, Isr. J. Chem. 1970, 8, 259.
S. L. Murov, I. Carmichael, G. L. Hug, Handbook of Photochemistry 2nd ed., Marcel Dekker Inc., New York 1993.
a) S. P. Pappas, UV-Curing: Science and Technology, Tech. Mark. Corp. Stamford, Plenum Press, New York 1986
b) J. P. Fouassier, D. Burr, J. V. Crivello, J. Photochem. Photobiol. A: Chem. 1989, 49, 317.
a) A. L. J. Beckwith, R. F. C. Claridge, J. A. Howard, Magnetic Properties of Free Radicals, Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology, Group II: Molecules and Radicals, Vol. 26, (Ed:, H. Fischer,), Springer Verlag, Berlin, Germany 2005
b) M. Kamachi, K. Tanaka, Y. Kuwae, J. Polym. Sci., Part A: Polym. Chem. 1986, 24, 925.
