Investigation of the surface activity of a poly(styrene-b-dimethylsiloxane) copolymer blended within a polystyrene matrix

Petitjean, Serge; Ghitti, G.; Jérôme, Robert; Teyssié, Philippe; Marien, José; Riga, Joseph; Verbist, Jacques

doi:10.1021/ma00093a014

Article (Scientific journals)

Investigation of the surface activity of a poly(styrene-b-dimethylsiloxane) copolymer blended within a polystyrene matrix

Petitjean, Serge; Ghitti, G.; Jérôme, Robert et al.

1994 • In Macromolecules, 27, p. 4127-4133

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DOI
10.1021/ma00093a014

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Keywords :

polymer blend

Abstract :

[en] The surface properties of thin polystyrene films are deeply modified by the addition of various amounts of a poly(styrene-b-dimethylsiloxane) copolymer-or poly(S-b-DMS)-as confirmed by a series of analytical methods. In addition to the surface tension which has been estimated from wettability and contact angle measurements, surface composition has been analyzed by X-ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS). Surface studies have been completed by the analysis of the depth distribution of siloxane from the surface by XPS and SIMS. Finally, the surface activity of poly(S-b-DMS) has been investigated in solution. Indeed, changes in the surface tension of polystyrene solutions in THF have been measured in relation to the addition of the diblock copolymer. All the experimental data agree with the complete coverage of the polystyrene films with the poly(S-b-DMS) copolymer. This situation already prevails in the solutions prepared as precursors to the thin polystyrene films. Accordingly, surface characteristics of film freshly prepared by solvent-casting are unaffected by subsequent annealing.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Petitjean, Serge; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Ghitti, G.; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Marien, José ; Université de Liège - ULiège > Laboratory of Physical Chemistry of Surfaces

Riga, Joseph; University of Namur (FUNDP) > Laboratoire Interdisciplinaire de Spectroscopie Electronique (LISE)

Verbist, Jacques; Univesity of Namur (FUNDP) > Laboratoire Interdisciplinaire de Spectroscopie Electronique (LISE)

Language :

English

Title :

Investigation of the surface activity of a poly(styrene-b-dimethylsiloxane) copolymer blended within a polystyrene matrix

Publication date :

18 July 1994

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Pages :

4127-4133

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma00093a014

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]

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