Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (meth)acrylic end-functionalized polymers: macromonomers and telechelics
[en] Tailor-made poly(tert-butyl acrylate) macromonomers, which are useful building blocks for the synthesis of comb or multiblock copolymers, have been successfully synthesized by deactivation of living PtBA macroanions with suitable electrophiles bearing either styrene or methacrylic unsaturation. Mono- or bifunctional initiators such as sec-butyllithium or naphthalenyllithium can be used. When these initiators were modified by LiCl as a mu-type ligand, the macroanions which are known to be living were functionalized with high efficiency. Characterization of the various macromonomers was performed using H-1 NMR spectroscopy and SEC.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Varshney, Sunil K; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Bayard, Philippe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jacobs, Christian; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Fayt, Roger; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (meth)acrylic end-functionalized polymers: macromonomers and telechelics
Publication date :
12 October 1992
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
American Chemical Society, Washington, United States - District of Columbia
Cipari, Luxembourg Norsolor, France BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique
Wiles, D. M. In Structure and Mechanism in Vinyl Polymerization; Tsurata, T., O'Driscoll, K. F., Eds.; Marcel Dekker: New York, 1969; p 233.
Jérôme, R.; Forte, R.; Varshney, S. K.; Fayt, R.; Teyssié, Ph. In Recent Advances in Mechanistic and Synthetic Aspects of Polymerization; Fontanille, M., Guyot, A., Eds.; NATO ASI, Ser. C; Kluwer: Dordrecht, The Netherlands, 1987; Vol. 215, p 101.
Fayt, R.; Forte, R.; Jacobs, C.; Jérôme, R.; Ouhadi, T.; Teyssié, Ph.; Varshney, S. K. Macromolecules 1987,20,1442.
Varshney, S. K.; Hautekeer, J. P.; Fayt, R.; Jérôme, R.; Teyssié, Ph. Macromolecules 1990, 23, 2618.
Varshney, S. K.; Jacobs, C.; Hautekeer, J. P.; Bayard, Ph.; Jérôme, R.; Fayt, R.; Teyssié, Ph. Macromolecules 1991, 24, 4997.
Hautekeer, J. P.; Varshney, S. K.; Fayt, R.; Jacobs, C.; Jérôme, R.; Teyssié, Ph. Macromolecules 1990, 23, 3893.
DePorter, C. D.; Venkateshwaran, L. N.; York, G. A.; Wilkes, G. L.; McGrath, J. E. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1989, 30,1, 201.
Claes, P.; Smets, G. Makromol. Chem. 1961, 44-46, 212.
Smith, S. D. Polym.Prepr. (Am. Chem. Soc.,Div. Polym. Chem.) 1989, 29, 2, 48.
Leebrick, J. R.; Remeden, H. E. J. Org. Chem. 1958,23, 935.
Antolin, K.; Lamps, J. P.; Rempp, P.; Gnanou, Y. Polymer 1990,31,967.
Wang, J. S.; Jérôme, R.; Teyssié, Ph. J. Polym. Sci., Polym. Chem. Ed., in press.
Reuter, H.; Berlinova, I. V.; Höring, S.; Ulbricht, J. Eur. Polym. J. 1991, 27, 7, 673.
Mason, J. P.; Hattori, T.; Hogen-Esch, T. E. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1989, 30, 1, 259.
Wagener, K. B.; Wanigatunga, S. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1986, 27,1,105.
