Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (meth)acrylic end-functionalized polymers: macromonomers and telechelics

Varshney, Sunil K; Bayard, Philippe; Jacobs, Christian; Jérôme, Robert; Fayt, Roger; Teyssié, Philippe

doi:10.1021/ma00047a003

Article (Scientific journals)

Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (meth)acrylic end-functionalized polymers: macromonomers and telechelics

Varshney, Sunil K; Bayard, Philippe; Jacobs, Christian et al.

1992 • In Macromolecules, 25 (21), p. 5578-5584

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DOI
10.1021/ma00047a003

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Keywords :

anionic polymerization; (meth)acrylate

Abstract :

[en] Tailor-made poly(tert-butyl acrylate) macromonomers, which are useful building blocks for the synthesis of comb or multiblock copolymers, have been successfully synthesized by deactivation of living PtBA macroanions with suitable electrophiles bearing either styrene or methacrylic unsaturation. Mono- or bifunctional initiators such as sec-butyllithium or naphthalenyllithium can be used. When these initiators were modified by LiCl as a mu-type ligand, the macroanions which are known to be living were functionalized with high efficiency. Characterization of the various macromonomers was performed using H-1 NMR spectroscopy and SEC.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Varshney, Sunil K; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Bayard, Philippe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jacobs, Christian; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Fayt, Roger; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (meth)acrylic end-functionalized polymers: macromonomers and telechelics

Publication date :

12 October 1992

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Issue :

Pages :

5578-5584

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma00047a003

Funders :

Cipari, Luxembourg
Norsolor, France
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]

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