The authors acknowledge Polymer Bulletin (Springer) for allowing them to archive this paper. The original publication is available at http://www.springerlink.com/content/uq7455h244p424w3/fulltext.pdf
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[en] The electrical conductivity of carbon-black loaded polystyrene-polyisoprene blends has been studied. In this ternary system, the filler is at the interface of co-continuous polyblends as confirmed by the very low value of the filler percolation threshold (0.2 vol % for blends compression molded at 250 degrees C) and by optical microscopy. As a result of the selective localization of carbon black at the interface, the percolation threshold is very sensitive to the compression molding temperature.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Soares, Bluma G; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Gubbels, Frédéric; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Vanlathem, Eric; Université Libre de Bruxelles (ULB) > Service de Physique des Solides
Deltour, Robert; Université Libre de Bruxelles (ULB) > Service de Physique des Solides
Language :
English
Title :
Electrical conductivity in carbon black-loaded polystyrene-polyisoprene blends. Selective localization of carbon black at the interface
Publication date :
July 1995
Journal title :
Polymer Bulletin
ISSN :
0170-0839
eISSN :
1436-2449
Publisher :
Springer Verlag, New York, United States - New York
The "Conselho Nacional de desenvolvimento Cientifico e Tecnologico" BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
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Bibliography
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Sumita M., Sakata K., Asai S., Miyasaka K., Nakagawa H. Poly. Bull. 1991, 25:265.
Sumita M., Abe H., Kayaki H., Miyasaka K. (1986) Effect of melt viscosity and surface tension of polymers on the percolation threshold of conductive-particle-filled polymeric composites. Journal of Macromolecular Science, Part B 25:171.
Asai S., Sakata K., Sumita M.M., Miyasaka K. Polym. J. 1992, 24:415.
Geuskens G., Gielens J.L., Geshef D., Deltour R. Eur. Polym. J. 1987, 23:993.
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