[en] Tailored polymerization of acrylic and methacrylic esters, particularly methyl methacrylate (MMA), has been the topic of a frantic research effort during the last decade. It is the purpose of this paper to present one of the main lines of that quest, and to evaluate its potential versus other new approaches.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Bayard, Philippe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Varshney, Sunil K; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Wang, Jin-Shan; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Heim, Philippe; Elf-Atochem, Groupement de Recherche de Lacq, France
Vuillemin, Bruno; Elf-Atochem, Groupement de Recherche de Lacq, France
Language :
English
Title :
Control of living anionic polymerization of (meth)acrylates : active complex species, macromolecular engineering and possible scaling-up
Collins S., Ward D.G. J. Am. Chem. Soc. 1992, 114:5460.
Inoue S., Aida T., Kuroki M., Hosokawa Y. (1990) Living polymerizations of acrylic monomers with aluminioporphyrin. Makromolekulare Chemie. Macromolecular Symposia 32:255.
Yamamoto T., Yamamoto A., Ikeda S. (1972) Activation of Iron-Alkyl Bonds in Dialkylbis (dipyridyl) iron(II) by Interaction with Olefins. Bulletin of the Chemical Society of Japan , 1111; 45:1104.
Ozawa F., Hayashi T., Koide H., Yamamoto A., J. Chem. Soc., Chem. Commun.; 1991, 1469.
Yasuda H., Yamamoto H., Takemoto Y., Yamashita M., Yokota K., Miyake S., Nakamure A. (1993) Novel synthesis of high molecular weight polymers with extremely low polydispersity by the unique initiation properties of organo-lanthanide complexes. Makromolekulare Chemie. Macromolecular Symposia 67:187.
Mardare D., Matyjaszewski K. Macromolecules 1994, 27:645.
Harwood H.J., and al, 35th IUPAC Int. Symp. on Macromolecules, Akron (July 1994), abstracts 0–1.1–2M and 0–1.1–8M.; .
Wayland B.B., Poszmik G., Mukerjee S.L. (1994) Living Radical Polymerization of Acrylates by Organocobalt Porphyrin Complexes. Journal of the American Chemical Society 116:7943.
Hatada K., Ute K., Tanaka K., Okamoto Y., Kitayama T. Polym. Bull. (Berlin) 1986, 18:1037.
Lochmann L., Rodova M., Trekoval J. J. Polym. Sci., Polym. Chem. Ed. 1974, 12:2091.
Lochmann L., Trekoval J., b, U.S. Patent 4,056,580, Nov.; 1977.
1980.
Lochmann L., Trekoval J. J. Polym. Sci., Polym. Chem. Ed. 1979, 17:1727.
Dvoranek L., Vlcek P. (1993) Anionic polymerization of acrylates. Polymer Bulletin 31:393.
Ouhadi T., Forte R., Jérǒme R., Fayt R., Teyssié, a, Luxembourg Patent 85.627; 1984.
1988.
Fayt R., Forte R., Jacobs C., Jérǒme R., Ouhadi T., Teyssié, Varshney S.K. Macromolecules 1987, 20:1442.
Varshney S.K., Hautekeer J.P., Fayt R., Jérǒme R., Teyssié Macromolecules 1990, 23:2618.
Varshney S.K., Jérǒme R., Bayard, Jacobs C., Fayt R., Teyssié Macromolecules 1992, 25:4457.
Wang J.S., Jérǒme R., Warin R., Zhang H., Teyssié Macromolecules 1994, 27:3376.
Wang J.S., Jérǒme R., Warin R., Teyssié Macromolecules 1993, 26:6776.
Macromolecules 1994, 27:1691.
Wang J.S., Jérome R., Teyssié, J. Phys. Org. Chem. (special issue), in press; .
Müller A. Makromol. Chem. 1992, 193:101.
Jacobs C., Varshney S.K., Hautekeer J.P., Fayt R., Jérǒme R., Teyssié Macromolecules 1990, 23:4024.
Bayard, Fayt R., Teyssié, Varshney S.K., a, French Patent 9109172, July; 1991.
Bayard, Jérǒme R., Teyssié, Varshney S.K., Wang J.S. Polym. Bull. (Berlin) 1994, 32:381.
Wang J.S., Bayard, Jérǒme R., Varshney S.K., Teyssié Macromolecules 1994, 27:4890.
Varshney S.K., Hautekeer J.P., Fayt R., Jérǒme R., Teyssié Macromolecules 1990, 23:2618.
Wang J.S., Jérǒme R., Warin R., Teyssié Macromolecules 1993, 26:5984.
Fayt R., Forte R., Jacobs C., Jérǒme R., Ouhadi T., Teyssié, Varshney S.K. Macromolecules 1987, 20:1442.
Hautekeer J.P., Varshney S.K., Fayt R., Jacobs C., Jérǒme R., Teyssié Macromolecules 1990, 23:3893.
Wang J.S., Teyssié, Heim, Vuillemin B., a, French Patent 94,01767, Feb.; 1994.
Wang J.S., Bayard, Jérǒme R., Baylac L., Patin M., Teyssié, b, Macromolecules in press.; .
Wang J.S., Jérǒme R., Bayard, Patin M., Teyssié, c, Macromolecules in press; .
Hautekeer J.P., Varshney S.K., Fayt R., Jérǒme R., Teyssié Macromolecules 1990, 23:3893.
Forte R., Ouhadi T., Fayt R., Jérǒme R., Teyssié J. Polym. Sci., Polym. Chem. 1990, 28:2233.
Teyssié, Fayt R., Jacobs C., Jérǒme R., Leemans L., Varshney S.K. Polym. Prep. (ACS Polym. Chem. Div.) 1988, 28(2):52.
Tung L.H., Lo G.Y.‐S. Macromolecules 1994, 27:2219.
Teyssié, Fayt R., Jacobs C., Jérǒme R., Varshney S.K. Polym. Prep. (ACS Polym. Chem. Div.) 1991, 32(1):449.
Jérǒme R., Bayard, Varshney S.K., Jacobs C., Teyssié, b, in “Thermoplastic Elastomers”; .
Antolin K., Lamps J.P., Rempp P., Gnanou Y. Polymer 1990, 31:967.
Gnanou Y., Rempp P. Die Makromolekulare Chemie 1988, 189:1997.
Varshney S.K., Bayard, Jacobs C., Jérǒme R., Fayt R., Teyssié Macromolecules 1992, 25:5578.
Varshney S.K., Bayard, Jacobs C., Jérǒme R., Fayt R., Teyssié Macromolecules 1990, 23:3893.
Maus C., Fontaine F., van den Bossche G., Sobry R., Jérǒme R. Journal de Physique IV 1993, 3(8 C):67.
Teyssié, in “Frontiers in Polymerization” (Liège Symposium, October), Makromol. Chem., Macromol. Symp., in press; 1993.