Recent advances in ring-opening polymerization of lactones and related compounds

Lögfren, Anders; Albertsson, Ann-Christine; Dubois, Philippe; Jérôme, Robert

doi:10.1080/15321799508014594

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Article (Scientific journals)

Recent advances in ring-opening polymerization of lactones and related compounds

Lögfren, Anders; Albertsson, Ann-Christine; Dubois, Philippe et al.

1995 • In Journal of Macromolecular Science. Reviews in Macromolecular Chemistry and Physics, C35 (3), p. 379-418

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10.1080/15321799508014594

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Keywords :

ring-opening polymerization (ROP); lactone; review

Abstract :

[en] Polyesters are currently synthesized by a step-growth mechanism from a mixture of a diol and a diacid (or a diacid derivative), or from a hydroxy-acid when available. Ring-opening polymerization (ROP) of lactones and related compounds is an alternative method for the synthesis of aliphatic polyesters. Comparison of these two mechanisms is clearly in favor of the polyaddition process. The drawbacks of polycondensation are well known:high temperatures and long reaction times are required to produce high-molecular-weight chains. Even though conversion of the hydroxyl and acid group is close to completion, any departure from the reaction stoichiometry has a very detrimental effect on the chain length.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Lögfren, Anders; The Royal Institute of Technology, Stockholm, Sweden > Department of Polymer Technology

Albertsson, Ann-Christine; The Royal Institute of Technology, Stockholm, Sweden > Department of Polymer Technology

Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Recent advances in ring-opening polymerization of lactones and related compounds

Publication date :

1995

Journal title :

Journal of Macromolecular Science. Reviews in Macromolecular Chemistry and Physics

ISSN :

0736-6574

Publisher :

Taylor & Francis

Volume :

C35

Issue :

Pages :

379-418

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.informaworld.com/smpp/ftinterface~db=all~content=a756863001~fulltext=713240930

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The Swedish Board for Technical Development (NUTEK)

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since 29 June 2009

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203

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182

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