Article (Scientific journals)
Acidic degradation of zeolite catalysts in the course of aromatic chlorination using sulfuryl chloride
Antenucci, Diano; Delaude, Lionel; Fransolet, André-Mathieu et al.
1992In Journal of Catalysis, 135 (1), p. 92-98
Peer Reviewed verified by ORBi
 

Files


Full Text
A005.pdf
Publisher postprint (637.46 kB)
Download

All documents in ORBi are protected by a user license.

Send to



Details



Abstract :
[en] The structural changes of two faujasite type zeolites in the course of aromatic chlorinations by sulfuryl chloride, SO2Cl2, were investigated by X-ray powder diffraction. Both catalysts examined, the NaX zeolite, which promotes catenar side-chain chlorination, and the ZF520 zeolite, which promotes nuclear electrophilic chlorination, are strongly altered in the acidic reaction medium (hydrochloric acid and sulfur dioxide are evolved continually as the reaction proceeds). In the presence of residual humidity, progressive dealumination of the ZF520 catalyst occurs without destruction of the zeolite framework. It gives rise to the formation of an alum type structure, for which the molecular formula (H3O)Al(SO4)2.12 H2O has been suggested. Rapid degradation of the NaX zeolite is accompanied by the formation of sodium chloride and of the sodium aluminium sulfate hexahydrate, NaAl(SO4)2.6 H2O. These compounds indeed catalyze the side-chain chlorination of toluene by SO2Cl2. Under water exclusion, structural degradation of both zeolites is slowed down; formation of hydrated sulfates is prevented; however the efficiency of the catalysts is also reduced.
Disciplines :
Chemistry
Author, co-author :
Antenucci, Diano
Delaude, Lionel  ;  Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Fransolet, André-Mathieu ;  Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Laszlo, Pierre ;  Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Acidic degradation of zeolite catalysts in the course of aromatic chlorination using sulfuryl chloride
Publication date :
1992
Journal title :
Journal of Catalysis
ISSN :
0021-9517
eISSN :
1090-2694
Publisher :
Academic Press, San Diego, United States - California
Volume :
135
Issue :
1
Pages :
92-98
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 26 June 2009

Statistics


Number of views
133 (2 by ULiège)
Number of downloads
61 (0 by ULiège)

Scopus citations®
 
17
Scopus citations®
without self-citations
16
OpenCitations
 
13

Bibliography


Similar publications



Contact ORBi