Article (Scientific journals)
Regioselective hydrochlorination of olefins is favored by an acidic solid catalyst
Delaude, Lionel; Laszlo, Pierre
1991In Tetrahedron Letters, 32 (30), p. 3705-3708
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Keywords :
Markovnikov; Anti-Markovnikov; Ionic; Radical; High Yield and Selectivity
Abstract :
[en] With thionyl chloride SOCl2 as HCl precursor, 1-methylcyclohexene is hydrochlorinated. In the absence of a solid catalyst, between half and two-thirds of the product mixture are the anti-Markovnikov adduct, trans 1-chloro-2-methyl cyclohexane. Catalysis by the ZF 520 zeolite or the K10 montmorillonite makes the reaction selective. It then affords a quantitative yield of (10:1) Markovnikov adduct 1-chloro-1-methylcyclohexane.
Disciplines :
Chemistry
Author, co-author :
Delaude, Lionel  ;  Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Laszlo, Pierre ;  Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Regioselective hydrochlorination of olefins is favored by an acidic solid catalyst
Publication date :
1991
Journal title :
Tetrahedron Letters
ISSN :
0040-4039
Publisher :
Elsevier, Oxford, United Kingdom
Volume :
32
Issue :
30
Pages :
3705-3708
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 26 June 2009

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