azide; Cu complexes; Ni complexes; Pd complexes; Staudinger reaction
Abstract :
[en] Two tripodal alcohols, viz., 1,1,1-tris(hydroxymethyl) ethane and alpha, alpha, alpha-tris(hydroxymethyl) toluene were converted by an efficient multi-step pathway involving azide formation into the corresponding tris(iminophosphorane) scaffolds bearing cyclopentyl (Cp) or phenyl groups on their phosphorus atoms, R-C(CH2-N] PR'(3))(3) (R Me or Ph, R'=Cp or Ph). The synthesis of some representative transition-metal complexes of Cu(I), Cu(II), Ni(II), and Pd(II) bearing these new tridentate ligands is also reported. (C) 2007 Elsevier Ltd. All rights reserved.
Disciplines :
Chemistry
Author, co-author :
Beaufort, Laurence
Delaude, Lionel ; Université de Liège - ULiège > Chimie macromoléculaire et catalyse organique
Noels, Alfred ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
A new tripodal ligand system based on the iminophosphorane functional group. Part 1: Synthesis and characterization
Publication date :
2007
Journal title :
Tetrahedron
ISSN :
0040-4020
Publisher :
Pergamon-Elsevier Science Ltd, Oxford, United Kingdom
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