Investigation of methyl methacrylate and vinyl acetate polymerization promoted by Al(iBu)3/2,2'-bipyridine and Al(iBu)3/2,2'-bipyridine/TEMPO complexes

Granel, Claude; Jérôme, Robert; Teyssié, Philippe; Jasieczek, C. B.; Shooter, A. J.; Haddleton, D. M.; Hastings, J. J.; Gigmes, D.; Grimaldi, S.; Tordo, P.; Greszta, D.; Matyjaszewski, K.

doi:10.1021/ma980006x

Article (Scientific journals)

Investigation of methyl methacrylate and vinyl acetate polymerization promoted by Al(iBu)3/2,2'-bipyridine and Al(iBu)3/2,2'-bipyridine/TEMPO complexes

Granel, Claude; Jérôme, Robert; Teyssié, Philippe et al.

1998 • In Macromolecules, 31 (21), p. 7133-7141

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/14953

DOI
10.1021/ma980006x

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Keywords :

polymerization; (meth)acrylate; vinyl acetate

Abstract :

[en] Results of methyl methacrylate (MMA) and vinyl acetate (VOAc) polymerization using the Al(iBu)3/2,2‘-bipyridine/TEMPO initiating system at room temperature failed to confirm the “living” radical mechanism reported earlier. Several species apparently propagate without control in a normal free radical process and only above a critical initiator concentration. No evidence was found for the penta- and hexacoordinated aluminum species previously suggested, but high conversion to an alkoxyamine was observed. Additionally, mixing Al(iBu)3 and BIPY promotes a variety of reactions involving alkyl and hydride transfers to the aromatic rings forming reduced BIPY products, along with a persistent organoaluminum radical. All these results illustrate that the process is considerably more complicated than postulated before. Conversely, at −78 °C, a single active species excluding the participation of TEMPO has been put in evidence, displaying some “living” characteristics. Several experiments support its anionic nature, as previously suggested by Ikeda.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Granel, Claude; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jasieczek, C. B.; University of Warwick, UK > Department of Chemistry

Shooter, A. J.; University of Warwick, UK > Department of Chemistry

Haddleton, D. M.; University of Warwick, UK > Department of Chemistry

Hastings, J. J.; University of Warwick, UK > Department of Chemistry

Gigmes, D.; Centre de Saint Jérôme, Marseille, France > Laboratoire de Structure et Réactivité des Espèces Paramagnétiques

Grimaldi, S.; Centre de Saint Jérôme, Marseille, France > Laboratoire de Structure et Réactivité des Espèces Paramagnétiques

Tordo, P.; Centre de Saint Jérôme, Marseille, France > Laboratoire de Structure et Réactivité des Espèces Paramagnétiques

Greszta, D.; Carnegie Mellon University, Pittsburgh, USA > Department of Chemistry

Matyjaszewski, K.; Carnegie Mellon University, Pittsburgh, USA > Department of Chemistry

Language :

English

Title :

Investigation of methyl methacrylate and vinyl acetate polymerization promoted by Al(iBu)3/2,2'-bipyridine and Al(iBu)3/2,2'-bipyridine/TEMPO complexes

Publication date :

20 October 1998

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

7133-7141

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma980006x
http://pubs.acs.org/doi/suppl/10.1021/ma980006x/suppl_file/ma980006x_s.pdf

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
Elf Atochem

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since 19 June 2009

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