radical polymerization; atom transfer radical polymerization (ATRP); thermoplastic elastomer; nanostructured material; self-assembly in bulk
Abstract :
[en] We investigate the microscopic morphology of thin films of symmetric triblock copolymers synthesized via a two-step “living” radical polymerization of n-butylacrylate and methyl methacrylate. These copolymers with low poly(methyl methacrylate) contents constitute a new class of potential thermoplastic elastomers with higher service temperature and oxidation resistance compared to conventional polydiene−polystyrene-based thermoplastic elastomers. The straightforward synthetic pathway allows for strict control of molecular weight, molecular-weight distribution, and composition. The presence in the copolymer of immiscible segments covalently bound to each other leads to phase separation on the nanometer scale. Regular organization of the phase-separated nanodomains is observed in real space by scanning force microscopy. The data point to a strong contrast in the local mechanical properties, corresponding to the microphase morphology. Cylinders of the minority phase are found to orient perpendicular to the surface, because of the surface energy difference between the constituents. Lamellae are also arranged perpendicular to the surface, in contrast to what is usually observed in block copolymers. This particular orientation is thought to result from the symmetric character of these triblock systems, with the outer blocks more polar than the central sequence.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Leclère, Philippe; University of Mons-Hainaut (UMH) > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires
Moineau, Georges; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Minet, Michaël; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Dubois, Philippe ; University of Mons-Hainaut (UMH) > Laboratory of Polymeric and Composite Materials (SMPC)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Brédas, Jean-Luc; University of Mons-Hainaut (UMH) > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires
Lazzaroni, Roberto; University of Mons-Hainaut (UMH) > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires
Language :
English
Title :
Direct observation of microdomain morphology in "all-acrylic" thermoplastic elastomers synthesized via living radical polymerization
Publication date :
25 May 1999
Journal title :
Langmuir
ISSN :
0743-7463
eISSN :
1520-5827
Publisher :
Amer Chemical Soc, Washington, United States - Washington
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique the European Commission and the Government of the "Région Wallonne" (Project NOMAPOL-Objectif1-Hainaut) F.R.S.-FNRS - Fonds de la Recherche Scientifique IBM Elf Atochem
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Gallot, B. R. M. Adv. Polym. Sci. 1978, 29, 85. Gallot, B. In Liquid Crystalline Order in Polymers; Blumstein, A., Ed.; Academic Press: New York, 1978; p 223. Hashimoto, T.; Nagatoshi, K.; Todo, A.; Hasegawa, H.; Kawai, H. Macromolecules 1974, 7, 364. Hashimoto, T.; Todo, A.; Itoi, H.; Kawai, H. Macromolecules 1977, 10, 377. Todo, A.; Kiuno, H.; Miyoshi, K.; Hashimoto, T.; Kawai, H. Polym. Eng. Sci. 1977, 17, 587. Hashimoto, T.; Shibayama, M.; Kawai, H. Macromolecules 1980, 13, 1237. Hashimoto, T.; Fujimura, M.; Kawai, H. Macromolecules 1980, 13, 1660. Thomas, E. L.; Anderson, D. M.; Henkee, C. S.; Hoffman, D. Nature 1988, 334, 598. Riess, G.; Bahhadur, P. In Encyclopedia of Polymer Science and Engineering; Mark, H. F., Bikales, N. M., Overberger, C. G., Menges, G., Eds.; Wiley: New York, 1989; p 324.
Szwarc, M.; Levy, M.; Milkovich, R. J. Am. Chem. Soc. 1956, 78, 2656.
Holden, G.; Legge, N. R. In Thermoplastic Elastomers - A Comprehensive Review; Holden, G., Legge, N. R., Schroeder, H. E., Eds.; Hanser: Munich, 1987; Chapter 3.
Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721. Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614. Moineau, G.; Minet, M.; Dubois, Ph.; Teyssié, Ph.; Senninger, T.; Jérôme, R. Macromolecules 1999, 32, 27.
Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721. Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614. Moineau, G.; Minet, M.; Dubois, Ph.; Teyssié, Ph.; Senninger, T.; Jérôme, R. Macromolecules 1999, 32, 27.
Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721. Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614. Moineau, G.; Minet, M.; Dubois, Ph.; Teyssié, Ph.; Senninger, T.; Jérôme, R. Macromolecules 1999, 32, 27.
Jérôme, R.; Bayard, P.; Fayt, R.; Jacobs, C.; Varshneyan, S. K.; Teyssié, Ph. In Thermoplastic Elastomers, 2nd ed.; Holden, G., Legge, N. R., Schroeder, H. E., Eds.; Hanser: Munich, 1996; p 521.
Zhong, Q.; Inniss, D.; Kjoller, K.; Elings, V. B Surf. Sci. 1993, 290, L688.
Leclère, Ph.; Lazzaroni, R.; Brédas, J. L.; Yu, J. M.; Dubois, Ph.; Jérôme, R. Langmuir 1996, 12, 4317.
Bar, G.; Thomman, Y.; Brandsch, R.; Cantow, H. J.; Whangbo, M. H. Langmuir 1997, 13, 3807.
Magonov, S. N.; Elings, V.; Whangbo, W. H. Surf. Sci. Lett. 1997, 575, L385.
Burnham, N. A.; Behrend, O. P.; Oulevey, F.; Gremaud, G.; Gallo, P.-J.; Gourdon, D.; Dupas, E.; Kulik, A. J.; Pollock, H. M.; Briggs G. A. D. Nanotechnology 1997, 8, 67.
Van den Berg, R.; De Groot, H.; Van Dijk, M. A.; Denley, D. R. Polymer 1994, 35, 5778.
Brandsch, R.; Bar, G.; Whangbo, M.-H. Langmuir 1997, 13, 6349.
Bar, G.; Brandsch, R.; Whangbo, M.-H. Langmuir 1997, 14, 7343.
Cleveland, J. P.; Anczykowski, B.; Schmidt, A. E.; Elings, V. B. Appl. Phys. Lett. 1998, 72, 2613.
Pickering, J. P.; Vancso, G. J. Polym. Bull. 1998, 40, 549.
Kopp, S.; Leclère, Ph.; Lazzaroni, R.; Aimé, J. P., to be published.
Van Krevelen, D. W. Properties of Polymers, 3rd ed.; Elsevier: Amsterdam, 1990; p 790.
Bates, F. S.; Fredrickson, G. H. Annu. Rev. Phys. Chem. 1990, 41, 525.
Van Dijk, M. A.; Van den Berg, R. Macromolecules 1995, 28, 6773. Wong, G. C. L.; Commandeur, J.; Fisher, H.; de Jeu, W. H. Phys. Rev. Lett. 1996, 77, 5221.
Van Dijk, M. A.; Van den Berg, R. Macromolecules 1995, 28, 6773. Wong, G. C. L.; Commandeur, J.; Fisher, H.; de Jeu, W. H. Phys. Rev. Lett. 1996, 77, 5221.
Heier, J.; Kramer, E. J.; Walheim, S.; Krausch, G. Macromolecules 1997, 30, 6610.
Tong, J. D.; Moineau, G.; Jérôme, R.; Leclére, Ph.; Brédas, J. L.; Lazzaroni, R., submitted for publication.
Han, C. D.; Kim, J.; Kim, J. K. Macromolecules 1989 22, 383. Collin, B.; Chatenay, D.; Coulon, G.; Ausserre, D.; Galot, Y. Macromolecules 1992, 25, 1621.
Han, C. D.; Kim, J.; Kim, J. K. Macromolecules 1989 22, 383. Collin, B.; Chatenay, D.; Coulon, G.; Ausserre, D.; Galot, Y. Macromolecules 1992, 25, 1621.
Similar publications
Sorry the service is unavailable at the moment. Please try again later.
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.
