[en] The behavior under shear of solutions of α,ω-lithium sulfonato polystyrene (α,ω-LiPSS100) in toluene has been investigated by rheo-optics and rheology. Shear-thickening is observed and related to a strong increase of birefringence and a pronounced and rapid alignment of the polymer chains toward the flow direction leading to an important elasticity of the fluids. The draw ratio of the polymer chains under shear has been estimated from the rheo-optical data. When the fraction of loops is taken into account, draw ratios on the order of 4 are calculated in the shear thickening regime.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Chassenieux, Christophe; Université du Maine, Le Mans, France > Chimie et Physique des Matériaux Polymères, UMR CNRS 6515
Tassin, Jean-François; Université du Maine, Le Mans, France > Chimie et Physique des Matériaux Polymères, UMR CNRS 6515
Gohy, Jean-François; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Elongation of telechelic ionomers under shear: a rheological and rheo-optical study
Publication date :
07 March 2000
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
Amer Chemical Soc, Washington, United States - Washington
(a) Schlick, S. Ionomers: Characterization, Theory and Applications; CRC Press Inc.: New York, 1996.
(b) Tant, M. R.; Mauritz, M. R.; Wilkes, G. L. Ionomers: Synthesis, Structure, Properties and Applications; Blackie Academic & Professional: New York, 1997.
a) Broze, G.; Jérôme, K.; Teyssié, P.; Marco, G. Polym. Bull. 1981, 4, 241.
(b) Broze, G.; Jérôme, K.; Teyssié, P.; Gallot, B. J. Polym. Sci., Polym. Lett. Ed. 1981, 19, 415.
a) Johannsson, R.; Chassenieux, C.; Durand, D.; Nicolai, T.; Vanhoorne, P.; Jérôme, R. Macromolecules 1995, 28, 8504.
(b) Chassenieux, C.; Johannsson, R.; Durand, D.; Nicolai, T. Vanhoorne, P.; Jérôme, R. Colloids Surf. A 1996, 112, 155.
Tant, M. R.; Wilkes, G. L.; Kennedy, J. P. J. Appl. Polym. Sci. 1991, 42, 523.
Pedley, A. M.; Higgins, J. S.; Peiffer, D. G.; Rennie, A. R.; Staples, E. Polym. Commun. 1989, 30, 162.
Jérôme, R. in Telechelic Polymers: Synthesis and Applications; Goethals, E. J., Ed.; CRC Press: Boca Raton: FL, 1989; Chapter 11.
Peiffer, D. G.; Kaladas, J.; Duvdevani, I.; Higgins, J. S. Macromolecules 1987, 20, 1397.
Vanhoorne, P.; Maus, C.; Van der Bosche, G.; Fontaine, F.; Sobry, R.; Jérôme, R.; Stamm, M. J. Phys. IV 1993, 3 (C8), 63.
Fuller, G. Optical Rheometry of Complex Fluids; Oxford University Press: New York, 1995.
Janeschitz-Kriegl, H. Polymer Melt Rheology and Flow Birefringence; Springer-Verlag: Berlin, 1983.
Kuhn, W.; Grun, F. Kolloid Z. 1942, 101, 248.
a) Annable, T.; Buscall, R.; Ettelaie, R.; Whittlestone, D. J. Rheol 1993, 37, 695;
b) Annable, T.; Buscall, R.; Ettelaie, R. Colloids Surf. A 1996, 112, 97.
Yekta, A.; Duhamel, J.; Brochard, P.; Adiwidjaja, H.; Winnik, M. A. Macromolecules 1992, 26, 1829.
Tam, K. C.; Jenkins, R. D.; Winnik, M. A.; Bassett, D. R. Macromolecules 1998, 31, 4149.
Van Egmond, J. W. Curr. Opin. Colloid Interface Sci. 1998, 3, 385.
Witten, T. A.; Cohen, M. H. Macromolecules 1985, 18, 1915.
Marrucci, G.; Bhargava, S.; Cooper, S. L. Macromolecules 1993, 26, 6483.
Pedley, A. M.; Higgins, J. S.; Peiffer, D. G.; Rennie, A. R.; Staples, E. Polym. Commun. 1989, 30, 162.
a) Gurnee, E. F. J. Appl. Phys. 1954, 25, 1232.
(b) Stein, R. S. J. Appl. Phys. 1961, 32, 1280.
Assuming uniaxial deformation around stretching direction would not change drastically the results. The dominant term in the right-hand side of eq 4 is λ2/5N in both cases.
Roe, R. J.; Krigbaum, W. R. J. Appl. Phys. 1964, 35, 2215.
