[en] The two step synthesis of a new bolaamphiphile derived from alkenyl L-rhamnosides was described. The general synthetic strategy of bolaamphiphiles derived from L-rhamnose was based on a previous work describing the synthesis of bolaamphiphiles derived from D-xylose. The conformational properties of this new compound were investigated by FTIR spectroscopy in an aqueous film in order to obtain a reference for further studies about the membrane-interacting properties. Moreover, the surface activity of this new bolaamphiphile was analyzed by Langmuir balance technology
and was compared with that of the analogous bolaamphiphile derived from alkenyl D-xylosides. The findings indicate that the rhamnoside-based bolaform has an increased surface activity and a better ability to form aggregates than xyloside-based one.
Disciplines :
Biochemistry, biophysics & molecular biology
Author, co-author :
Gatard, Sylvain ✱
Nasir, Mehmet Nail ✱; Université de Liège - ULiège > Chimie et bio-industries > Chimie biologique industrielle
Deleu, Magali ; Université de Liège - ULiège > Chimie et bio-industries > Chimie biologique industrielle
Legrand, Vincent
Bouquillon, Sandrine
✱ These authors have contributed equally to this work.
Language :
English
Title :
Bolaamphiphiles Derived from Alkenyl L-rhamnosides and Alkenyl D-xylosides: Importance of the Hydrophilic Head
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