Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

dos Santos, D. A.; Kogej, T.; Brédas, Jean-Luc; Boutton, C.; Hendrickx, E.; Houbrechts, S.; Clays, K.; Persoons, A.; Xhang, J. X.; Dubois, Philippe; Jérôme, Robert

doi:10.1016/S0022-2860(99)00437-8

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Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

dos Santos, D. A.; Kogej, T.; Brédas, Jean-Luc et al.

2000 • In Journal of Molecular Structure, 521, p. 221-230

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/14749

DOI
10.1016/S0022-2860(99)00437-8

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Keywords :

nonlinear optics

Abstract :

[en] We present a joint theoretical and experimental investigation of the second-order nonlinear optical properties of a new kind of active molecule with a triblock structure. The molecular architecture is such that two highly polarizable conjugated segments are separated from each other by a spacer; one of the conjugated segments is end-capped with an electron-donor group, the other one by an acceptor. E-vinylthiophenes are used as the conjugated segments; N,N-dimethylaniline and nitrophenyl are selected as the donor-acceptor pairs, while the spacer consists of a nonconjugated moiety. Several spacers are considered and discussed with respect to their ability to modulate the charge transfer between the donor and acceptor ends.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

dos Santos, D. A.; University of Mons-Hainaut (UMH) > Centre de Recherche en Electronique et Photonique Moléculaires > Service de Chimie des Matériaux Nouveaux

Kogej, T.; University of Mons-Hainaut (UMH) > Centre de Recherche en Electronique et Photonique Moléculaires > Service de Chimie des Matériaux Nouveaux

Brédas, Jean-Luc; University of Mons-Hainaut (UMH) > Centre de Recherche en Electronique et Photonique Moléculaires > Service de Chimie des Matériaux Nouveaux

Boutton, C.; University of Leuven (KUL) > Center for Research on Molecular Photonics and Electronics > Laboratory of Chemical and Biological Dynamics

Hendrickx, E.; University of Leuven (KUL) > Center for Research on Molecular Photonics and Electronics > Laboratory of Chemical and Biological Dynamics

Houbrechts, S.; University of Leuven (KUL) > Center for Research on Molecular Photonics and Electronics > Laboratory of Chemical and Biological Dynamics

Clays, K.; University of Leuven (KUL) > Center for Research on Molecular Photonics and Electronics > Laboratory of Chemical and Biological Dynamics

Persoons, A.; University of Leuven (KUL) > Center for Research on Molecular Photonics and Electronics > Laboratory of Chemical and Biological Dynamics

Xhang, J. X.; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Novel functionalized oligo-vinylthiophene molecules with modulated second-order nonlinear optical response

Publication date :

28 March 2000

Journal title :

Journal of Molecular Structure

ISSN :

0022-2860

eISSN :

1872-8014

Publisher :

Elsevier Science Bv, Amsterdam, Netherlands

Volume :

521

Pages :

221-230

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TGS-409VM4J-N-1&_cdi=5262&_user=532038&_orig=browse&_coverDate=03%2F28%2F2000&_sk=994789998&view=c&wchp=dGLzVlz-zSkzV&md5=52df8d1586c492ef34cdf32e909519bd&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/500850/description#description

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture
FWO - Fonds Wetenschappelijk Onderzoek Vlaanderen
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Commentary :

The authors acknowledge Journal of Molecular Structure (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 17 June 2009

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Bibliography

Chemla D.S., Zyss J. Nonlinear Optical Properties of Organic Molecules and Crystals. 1987;Academic Press, Orlando.
Marder S.R., Sohn J.E., Stucky G.D. Materials for Nonlinear Optics: Chemical Perspectives. 1991;455 ACS Symposium Series, Washington, DC.
Zerbi G. Organic Materials for Photonics: Science and Technology. 1993;Elsevier, Amsterdam.
Brédas J.L., Silbey R. Conjugated Polymers: The Novel Science and Technology of Highly Conducting and Nonlinear Optically Active Materials. 1991;Kluwer Academic, Dordrecht.
Mignani G., Kramer A., Pucetti G., Ledoux I., Soula G., Zyss J. Mol. Eng. 1:1991;11.
Salhi N., Hedstrom M., Eriksson L.A., Calais J.L. Theochem. J. Mol. Struct. 94:1992;273.
Kogej T., Marder S.R., Silbey R., Brédas J.L. Synt. Met. 85:1997;1141.
Kogej T., Briche M.H., Silbey R., Marder S.R., Brédas J.L. Synt. Met. 2000;. in press.
Maertens C., Detrembleur C., Dubois Ph., Jérôme R., Boutton C., Persoons A., Kogej T., Brédas J.L. Chem. Eur. J. 5:1999;369.
Marder S.R., Gorman C.B., Meyers F., Perry J.W., Bourhill G., Brédas J.L., Pierce B.M. Science. 265:1994;632.
Meyers F., Marder S.R., Pierce B.M., Brédas J.L. J. Am. Chem. Soc. 116:1994;10 703.
Meyers F., Brédas J.L., Pierce B.M., Marder S.R. Chem. Phys. Lett. 228:1994;171.
Meyers F., Marder S.R., Pierce B.M., Brédas J.L. Nonlinear Optics. 9:1995;59.
Zhang J.-X., Dubois P., Jérôme R. J. Chem. Soc. Perkin Trans. 2:1997;1209.
Dewar M.J.S., Zoebish E.G., Healy E.F., Stewart J.J.P. J. Am. Chem. Soc. 107:1985;3902.
Kurtz H.A., Stewart J.J.P., Dieter K.M. J. Comput. Chem. 11:1990;82.
Ridley J.E., Zerner M.C. Theor. Chim. Acta. 32:1973;111.
Ridley J.E., Zerner M.C. Theor. Chim. Acta. 42:1976;223.
Morley J.O., Pavlides P., Pugh D. J. Chem. Soc. Faraday Trans. 85:1989;1789.
Morley J.O. J. Chem. Soc. Faraday Trans. 87:1991;3009.
Morley J.O., Pugh D. J. Chem. Soc. Faraday Trans. 87:1991;3021.
Morley J.O. J. Chem. Soc. Faraday Trans. 87:1991;3015.
Morley J.O. J. Am. Chem. Soc. 110:1988;7660.
Morley J.O., Docherty V.J., Pugh D. J. Chem. Soc. Perkin Trans. 2:1987;1361.
Morley J.O., Docherty V.J., Pugh D. J. Mol. Electron. 5:1989;117.
Morley J.O., Pavlides P., Pugh D. Int. J. Quant. Chem. 43:1992;7.
Karna S.P., Baskowski Z., Talapatra G.B., Prasad P.N. J. Phys. Chem. 95:1991;6508.
Teng C.C., Garito A.F. Phys. Rev. B. 28:1983;6766.
Waite J., Papadopoulos M.G. J. Phys. Chem. 94:1990;6244.
DeQuan L., Marks T.J., Ratner M.A. J. Phys. Chem. 96:1992;4325.
Shuai Z., Beljonne D., Brédas J.L. J. Chem. Phys. 97:1992;1132.
Ulman A., Willand C.S., Köhler W., Robello D.R., Williams D.J., Handley L. J. Am. Chem. Soc. 112:1990;7083.
Pierce B.M. J. Chem. Phys. 91:1989;791.
Kanis D.R., Marks T.J., Ratner M.A. Int. J. Quant. Chem. 43:1992;61.
Orr B.J., Ward J.F. Mol. Phys. 20:1971;513.
Clays K., Persoons A. Phys. Rev. Lett. 66:1991;2980.
Clays K., Persoons A. Rev. Sci. Instrum. 63:1992;3285.
Verbiest T., Clays K., Persoons A., Meyers F., Brédas J.L. Opt. Lett. 18:1993;525.
Verbiest T., Clays K., Samyn C., Wolff J., Reinhoudt D., Persoons A. J. Am. Chem. Soc. 116:1994;9320.
Zyss J., Dhenaut C., Chauvan T., Ledoux I. Chem. Phys. Lett. 206:1993;409.
Verbiest T., Hendrickx E., Persoons A., Clays K. Proc. Soc. Photo-Opt. Instrum. Eng. 1775:1992;206.
Laidlaw W.M., Denning R.G., Verbiest T., Chauchard E., Persoons A. Nature. 363:1993;58.
Behrens U., Brussaard H., Hagenau U., Heck J., Hendrickx E., Kornich J., Vanderlinden J.G.M., Persoons A., Spek A.L., Veldman N., Voss B., Wong H. Chem. Eur. J. 2:1996;98.
Clays K., Hendrickx E., Triest M., Verbiest T., Persoons A., Dehu C., Brédas J.L. Science. 262:1993;1419.
Verbiest T., Samyn C., Boutton C., Houbrechts S., Kauranen M., Persoons A. Adv. Mat. 8:1996;756.
Hendrickx E., Clays K., Persoons A., Dehu C., Brédas J.L. J. Am. Chem. Soc. 117:1995;3547.
Kauranen M., Verbiest T., Maki J.J., Persoons A. Synt. Met. 81:1996;117.
Maki J.J., Kauranen M., Persoons A. Phys. Rev. B. 51:1995;1425.
Willetts A., Rice J.E., Burland D.M., Shelton D.P. J. Chem. Phys. 97:1992;7590.
C. Adant, J.L. Brédas, unpublished data.
Zyss J. Brédas J.L., Chance R.R. Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics. NATO-ASI Series, Series E: Applied Sciences. 182:1989;545 Kluwer Academic, Dordrecht.