[en] We report our latest results on second harmonic generation (SHG) microscopy from arrays of G-shaped chiral gold nanostructures. The nanostructures are arranged in unit cells composed of four Gs, each rotated at 90° with respect to its neighbors. As it has already been demonstrated, for linearly polarized light, these unit cells yield a pattern of four SHG hotspots. However, upon increasing the pitch of the nanostructured arrays, extra hotspots can be observed at the edges of the unit cells. While the origin of these extra hotspots remains to be elucidated, their position indicates a relationship to coupling behavior between the unit cells.
Disciplines :
Physics
Author, co-author :
Valev, VK; Katholieke Universiteit Leuven - KUL
Osley, EJ; University College London - UCL
De Clercq, B; Universiteit Hasselt - UH
Silhanek, Alejandro ; Université de Liège - ULiège > Département de physique > Physique de la matière condensée
Warburton, PA; University College London - UCL
Aktsipetrov, OA; Lomonosov Moscow State University - MSU
Ameloot, M; Universiteit Hasselt - UH
Moshchalkov, VV; Katholieke Universiteit Leuven - KUL
Verbiest, T; Katholieke Universiteit Leuven - KUL
Language :
English
Title :
Second harmonic hotspots at the edges of the unit cells in G-shaped gold nanostructures
Publication date :
2012
Journal title :
Proceedings of SPIE: The International Society for Optical Engineering
ISSN :
0277-786X
eISSN :
1996-756X
Publisher :
International Society for Optical Engineering, Bellingham, United States - Washington
Jeanmaire, D.L., Van Duyne, R.P., Surface raman spectroelectrochemistry: Part 1. Heterocyclic, aromatic and aliphatic amines adsorbed on the anodized silver electrodes (1977) J. Electroanal. Chem., 84, pp. 1-20
Albrecht, M.G., Creighton, J.A., Anomalously intense Raman spectra of pyridine at a silver electrode (1977) J. Am. Chem. Soc., 99, pp. 5215-5217
Stockman, M.I., Surface-Enhanced Raman Scattering: Physics and Applications (2006) Top. Appl. Phys., 103, p. 47
Kneipp, K., Wang, Y., Kneipp, H., Perelman, L.T., Itzkan, I., Dasari, R.R., Feld, M.S., Single molecule detection using surface-enhanced raman scattering (sers) (1997) Phys. Rev. Lett., 78, p. 1667
Nie, S., Emory, S.R., Probing single molecules and single nanoparticles by surface-enhanced Raman scattering (1997) Science, 275, p. 1102
Valev, V.K., Kirilyuk, A., Rasing, Th., Dela Longa, F., Kohlhepp, J.T., Koopmans, B., Oscillations of the net magnetic moment and magnetization reversal properties of the Mn/Co interface (2007) Phys. Rev. B, 75, p. 012401
Lee, C.H., Chang, R.K., Bloembergen, N., Nonlinear electroreflectance in silicon and silver (1967) Phys. Rev. Lett., 18 (5), pp. 167-170
Kirilyuk, A., Rasing, Th., Magnetization-induced-second-harmonic generation from surfaces and interfaces (2005) J. Opt. Soc. Am. B, 22 (1), pp. 148-167
Valev, V.K., Gruyters, M., Kirilyuk, A., Rasing, Th., Influence of quadratic contributions in magnetization-induced second harmonic generation studies of magnetization reversal (2005) Phys. Stat. Sol. (B), 242, pp. 3027-3031
Sheng, Y., Best, A., Butt, H.-J., Krolikowski, W., Arie, A., Koynov, K., Three-dimensional ferroelectric domain visualization by Cerenkov-type second harmonic generation (2010) Opt. Express, 18 (16), pp. 16539-16545
Pavlov, V.V., Ferré, J., Meyer, P., Tessier, G., Georges, P., Brun, A., Beauvillain, P., Mathet, V., Linear and non-linear magneto-optical studies of Pt/Co/Pt thin films (2001) J. Phys. Condens. Matter, 13 (44), pp. 9867-9878
Abid, J.P., Nappa, J., Girault, H.H., Brevet, P.F., Pure Surface Plasmon Resonance Enhancement of the First Hyperpolarizability of Gold Core - Silver Shell Nanoparticles (2004) J. Chem. Phys., 121, p. 12577
Antoine, R., Péllarin, M., Prével, B., Palpant, B., Broyer, M., Galletto, P., Brevet, P.F., Girault, H.H., Surface Plasmon Enhanced Second Harmonic Response from Gold Clusters Embedded in an Alumina Matrix (1998) J. Appl. Phys., 84, p. 4532
Galletto, P., Brevet, P.F., Girault, H.H., Antoine, R., Broyer, M., Size Dependence of the Surface Plasmon Enhanced Second Harmonic Response of Gold Colloids: Towards a New Calibration Method (1999) Chem. Commun., 7, pp. 581-582
Russier-Antoine, I., Nappa, J., Benichou, E., Jonin, Ch., Brevet, P.F., Wavelength Dependence of the Hyper Rayleigh Scattering Response from Gold Nanoparticles (2004) J. Chem. Phys., 120, p. 10748
Nappa, J., Russier-Antoine, I., Benichou, E., Jonin, Ch., Brevet, P.F., Wavelength Dependance of the Retardation Effects in Silver Nanoparticles Followed by Polarization Resolved Hyper Rayleigh Scattering (2005) Chem. Phys. Lett., 415, p. 246
Nappa, J., Revillod, G., Abid, J.P., Russier-Antoine, I., Jonin, Ch., Benichou, E., Girault, H.H., Brevet, P.F., Hyper Rayleigh Scattering of Gold Nanorods and their relationship with linear assemblies of gold nanospheres (2004) Faraday Disc., 125, p. 145
Russier-Antoine, I., Duboisset, J., Bachelier, G., Benichou, E., Jonin, Ch., Del Fatti, N., Vallée, F., Brevet, P.F., Symmetry Cancellations in the Quadratic Hyperpolarizability of Non Centrosymmetric Gold Decahedra (2010) J. Phys. Chem. Lett., 1, p. 874
Nappa, J., Revillod, G., Russier-Antoine, I., Benichou, E., Jonin, Ch., Brevet, P.F., Electric Dipole Origin of the Second Harmonic Generation from Small Metallic Particles (2005) Phys. Rev. B, 71, p. 165407
Nappa, J., Russier-Antoine, I., Benichou, E., Jonin, Ch., Brevet, P.F., Second-harmonic light generation from small gold metallic particles: From the dipolar to the quadrupolar response (2006) J. Chem. Phys., 125, p. 184712
Russier-Antoine, I., Benichou, E., Bachelier, G., Jonin, Ch., Brevet, P.F., Multipolar Contributions of the Second Harmonic Generation from Silver and Gold Nanoparticles (2007) J. Phys. Chem. C, 111, p. 9044
Bachelier, G., Russier-Antoine, I., Benichou, E., Jonin, Ch., Brevet, P.F., Multipolar Second Harmonic Generation in Noble Metal Nanoparticles (2008) J. Opt. Soc. Am. B, 25, p. 955
Centini, M., Benedetti, A., Sibilia, C., Bertolotti, M., Coupled 2D Ag nano-resonator chains for enhanced and spatially tailored second harmonic generation (2011) Opt. Express, 19, pp. 8218-8232
Benedetti, A., Centini, M., Bertolotti, M., Sibilia, C., Second harmonic generation from 3D nanoantennas: On the surface and bulk contributions by far-field pattern analysis (2011) Opt. Express, 19, p. 26752
Benedetti, A., Centini, M., Sibilia, C., Bertolotti, M., Engineering the second harmonic generation pattern from coupled gold nanowires (2010) J. Opt. Soc. Am. B, 27 (3), pp. 408-416
Belardini, A., Larciprete, M.C., Centini, M., Fazio, E., Sibilia, C., Bertolotti, M., Toma, A., Buatier De Mongeot, F., Tailored second harmonic generation from self-organized metal nano-wires arrays (2009) Opt. Express, 17 (5), pp. 3603-3609
Belardini, A., Larciprete, M.C., Centini, M., Fazio, E., Sibilia, C., Chiappe, D., Martella, C., Buatier De Mongeot, F., Circular Dichroism in the Optical Second-Harmonic Emission of Curved Gold Metal Nanowires (2011) Phys. Rev. Lett., 107, p. 257401
Russier-Antoine, I., Huang, J., Benichou, E., Bachelier, G., Jonin, Ch., Brevet, P.F., Hyper Rayleigh Scattering of Protein-Mediated Gold Nanoparticles Aggregates (2008) Chem. Phys. Lett., 450, p. 345
Awada, Ch., Kessi, F., Jonin, Ch., Adam, P.M., Kostcheev, S., Bachelot, R., Royer, P., Brevet, P.F., On- and Off-Axis Second Harmonic Generation from an Array of Gold Metallic Nanocylinders (2011) J. Appl. Phys, 110, p. 023109
Biris, C.G., Panoiu, N.C., Excitation of dark plasmonic cavity modes via nonlinearly induced dipoles: Applications to near-infrared plasmonic sensing (2011) Nanotechnology, 22, p. 235502
Biris, C.G., Panoiu, N.C., Excitation of linear and nonlinear cavity modes upon interaction of femtosecond pulses with arrays of metallic nanowires (2011) Appl Phys A, 103, pp. 863-867
Cao, L., Panoiu, N.C., Osgood, R.M., Surface second-harmonic generation from surface plasmon waves scattered by metallic nanostructures (2007) Phys. Rev. B, 75, p. 205401
Smolyaninov, I.I., Zayats, A.V., Davis, C.C., Near-field second harmonic generation from a rough metal surface (1997) Phys. Rev. B, 56, pp. 9290-9293
Zayats, A.V., Kalkbrenner, T., Sandoghdar, V., Mlynek, J., Second-harmonic generation from individual surface defects under local excitation (2000) Phys. Rev. B, 61, p. 4545
Canfield, B.K., Kujala, S., Laiho, K., Jefimovs, K., Turunen, J., Kauranen, M., Chirality arising from small defects in gold nanoparticle arrays (2006) Opt. Express, 14, pp. 950-955
Zayats, A.V., Smolyaninov, I.I., Davis, C.C., Observation of localized plasmonic excitations in thin metal films with near-field second-harmonic microscopy (1999) Opt. Commun., 169, pp. 93-96
Anceau, C., Brasselet, S., Zyss, J., Gadenne, P., Local second-harmonic generation enhancement on gold nanostructures probed by two-photon microscopy (2003) Opt. Lett., 28, pp. 713-715
Valev, V.K., Silhanek, A.V., Smisdom, N., De Clercq, B., Gillijns, W., Aktsipetrov, O.A., Ameloot, M., Verbiest, T., Linearly Polarized Second Harmonic Generation Microscopy Reveals Chirality (2010) Optics Express, 18, pp. 8286-8293
Butet, J., Duboisset, J., Bachelier, G., Russier-Antoine, I., Benichou, E., Jonin, C., Brevet, P.-F., Optical Second Harmonic Generation of Single Metallic Nanoparticles Embedded in a Homogeneous Medium (2010) Nano Lett., 10, pp. 1717-1721
Butet, J., Bachelier, G., Duboisset, J., Bertorelle, F., Russier-Antoine, I., Jonin, C., Benichou, E., Brevet, P.-F., Three-dimensional mapping of single gold nanoparticles embedded in a homogeneous transparent matrix using optical second-harmonic generation (2010) Opt. Express, 18, pp. 22314-22323
Valev, V.K., Smisdom, N., Silhanek, A.V., De Clercq, B., Gillijns, W., Ameloot, M., Moshchalkov, V.V., Verbiest, T., Plasmonic Ratchet Wheels: Switching Circular Dichroism by Arranging Chiral Nanostructures (2009) Nano Lett., 9, p. 3945
Valev, V.K., Volodin, A., Silhanek, A.V., Gillijns, W., De Clercq, B., Jeyaram, Y., Paddubrouskaya, H., Verbiest, T., Plasmons reveal the direction of magnetization in nickel nanostructures (2011) ACS Nano, 5, pp. 91-96
Valev, V.K., Silhanek, A.V., De Clercq, B., Gillijns, W., Jeyaram, Y., Zheng, X., Volskiy, V., Verbiest, T., U-shaped switches for optical information processing at the nanoscale (2011) Small, 7, pp. 2573-2576
Valev, V.K., Silhanek, A.V., Jeyaram, Y., Denkova, D., De Clercq, B., Petkov, V., Zheng, X., Verbiest, T., Hotspot decorations map plasmonic patterns with the resolution of scanning probe techniques (2011) Phys. Rev. Lett., 106, p. 226803
Valev, V.K., Zheng, X., Biris, C.G., Silhanek, A.V., Volskiy, V., De Clercq, B., Aktsipetrov, O.A., Moshchalkov, V.V., The Origin of Second Harmonic Generation Hotspots in Chiral Optical Metamaterials (2011) Opt. Mater. Express, 1, pp. 36-45
Valev, V.K., De Clercq, B., Zheng, X., Denkova, D., Osley, E.J., Vandendriessche, S., Silhanek, A.V., Verbiest, T., The role of chiral local field enhancements below the resolution limit of Second Harmonic Generation microscopy (2012) Opt. Express, 20, pp. 256-264