[en] In this work, long-term antibacterial, antiadhesion, and antibiofilm activities are afforded to industrial stainless steel surfaces following a green and bio-inspired strategy. Starting from catechol bearing synthetic polymers, the film cross-linking and the grafting of active (bio)molecules are possible under environmentally friendly conditions (in aqueous media and at room temperature). A bio-inspired polyelectrolyte, a polycation-bearing catechol, is used as the film-anchoring polymer while a poly(methacrylamide)-bearing quinone groups serves as the cross-linking agent in combination with a polymer bearing primary amine groups. The amine/quinone reaction is exploited to prepare stable solutions of nanogels in water at room temperature that can be easily deposited to stainless steel. This coating provides quinonefunctionalized surfaces that are then used to covalently anchor active (bio) molecules (antibiofi lm enzyme and antiadhesion polymer) through thiol/ quinone reactions.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Faure, Emilie ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Falentin, Céline ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Svaldo Lanero, Tiziana ; Université de Liège - ULiège > Department of Chemistry > Nanochemistry and Molecular Systems (NANOCHEM)
Vreuls, Christelle ; Université de Liège - ULiège > GIGA-Research > Laboratoire de Biologie Moléculaire et de Génie Génétique
Zocchi, Germaine ; Université de Liège - ULiège > GIGA-Research > Laboratoire de Biologie Moléculaire et de Génie Génétique
Van de Weerdt, Cécile ; Université de Liège - ULiège > GIGA-Research > Laboratoire de Biologie Moléculaire et de Génie Génétique
Martial, Joseph ; Université de Liège - ULiège > GIGA-Research > Laboratoire de Biologie Moléculaire et de Génie Génétique
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Duwez, Anne-Sophie ; Université de Liège - ULiège > Department of Chemistry > Nanochemistry and Molecular Systems (NANOCHEM)
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Functional nanogels as platforms for imparting antibacterial, antibiofilm, and antiadhesion activities to stainless steel
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique The Walloon Region in the frame of the BIOCOAT program
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