[en] Polyester-grafted polyhedral oligomeric silsesquioxane (POSS) nanohybrids selectively produced by ring-opening polymerization of epsilon-caprolactone and L,L-lactide (A.-L. Goffin, E. Duquesne, S. Moins, M. Alexandre, Ph. Dubois, Eur. Polym. Journal, 2007, 43, 4103) were studied as ‘‘masterbatches’’ by melt-blending within their corresponding commercial polymeric matrices, i.e., poly(epsilon-caprolactone) (PCL) and poly(L,L-lactide) (PLA). For the sake of comparison, neat POSS nanoparticles were also dispersed in PCL and PLA. The objective was to prepare aliphatic polyester-based nanocomposites with enhanced crystallization behavior, and therefore, enhanced thermo-mechanical properties.
Wide-angle X-ray scattering and transmission electron microscopy attested for the dispersion of
individualized POSS nanoparticles in the resulting nanocomposite materials only when the polyester-grafted POSS nanohybrid was used as a masterbatch. The large impact of such finely dispersed (grafted) nanoparticles on the crystallization behavior for the corresponding polyester matrices was noticed, as evidenced by differential scanning calorimetry analysis. Indeed, well-dispersed POSS nanoparticles acted as efficient nucleating sites, significantly increasing the crystallinity degree of both PCL and PLA matrices. As a result, a positive impact on thermo-mechanical properties was highlighted by dynamic mechanical thermal analysis.
Disciplines :
Chemistry
Author, co-author :
Goffin, Anne-Lise; Université de Mons - UMONS > Center of Innovation and Research in Materials and Polymers (CIRMAP) > Laboratory of Polymeric and Composite Materials (LPCM)
Duquesne, Emmanuel; Université de Mons - UMONS > Center of Innovation and Research in Materials and Polymers (CIRMAP) > Laboratory of Polymeric and Composite Materials (LPCM)
Raquez, Jean-Marie; Université de Mons - UMONS > Center of Innovation and Research in Materials and Polymers (CIRMAP) > Laboratory of Polymeric and Composite Materials (LPCM)
Ke, Xiaoxing; Universiteit Antwerpen - UA > Electron Microscopy for Materials Science
Alexandre, Michaël ; Université de Mons - UMONS > Center of Innovation and Research in Materials and Polymers (CIRMAP) > Laboratory of Polymeric and Composite Materials (LPCM)
Van Tendeloo, Gustaaf; Universiteit Antwerpen - UA > Electron Microscopy for Materials Science
Van Mele, Bruno; Vrije Universiteit Brussel - VUB > Physical Chemistry and Polymer Science
Dubois, Philippe ; Université de Mons - UMONS > Center of Innovation and Research in Materials and Polymers (CIRMAP) > Laboratory of Polymeric and Composite Materials (LPCM)
Language :
English
Title :
From polyester grafting onto POSS nanocage by ring-opening polymerization to high performance polyester/POSS nanocomposites
Publication date :
02 June 2010
Journal title :
Journal of Materials Chemistry
ISSN :
0959-9428
eISSN :
1364-5501
Publisher :
Royal Society of Chemistry, Cambridge, United Kingdom
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Bibliography
A.-L. Goffin, E. Duquesne, S. Moins, M. Alexandre, Ph. Dubois Eur. Polym. J., 2007, 43, 4103.
P. G. Harrison J. Organomet. Chem., 1997, 542, 141.
www.hybridplastics.com
Y. Zhang, S. Lee, M. Yoonessi, K. Liang, C. U. Pittman Polymer, 2006, 47, 2984.
M. Joshi, B. S. Butola Polymer, 2004, 45, 4953.
A. Fina, H. C. L. Abbenhuis, D. Tabuani, A. Frache, G. Camino Polym. Degrad. Stab., 2006, 91, 1064.
B. X. Fu, L. Yang, R. H. Somani, S. X. Zong, B. S. Hsiao, S. Phillips, R. Blanski, P. Ruth J. Polym. Sci., Part B: Polym. Phys., 2001, 39, 2727.
Y. Zhao, D. A. Schiraldi Polymer, 2005, 46, 11640.
S. H. Phillips, T. S. Haddad, S. J. Tomczak Curr. Opin. Solid State Mater. Sci., 2004, 8, 21.
M. Z. Asuncion, R. M. Laine Macromolecules, 2007, 40, 555.
H. Rios-Dominguez, F. A. Ruiz-Trevino, R. Contreras-Reyes, A. Gonzales-Montiel J. Membr. Sci., 2006, 271, 94.
S. Bourbigot, S. Duquesne, Ch. Jamal Macromol. Symp., 2006, 233, 180.
A. Vannier, S. Duquesne, S. Bourbigot, A. Castrovinvi, G. Camino, R. Delobel Polym. Degrad. Stab., 2008, 93, 818.
Lei Song, Qingliang He, Yuan Hu, Hao Chen, Lei Liu Polym. Degrad. Stab., 2008, 93, 627.
A. Fina, D. Tabuani, A. Frache, G. Camino Polymer, 2005, 46, 7855.
L. Matejka, A. Strachota, J. Plestil, P. Whelan, M. Steinhart, M. Slouf Macromolecules, 2004, 37, 9449.
S. Y. Soong, R. E. Cohen, M. C. Boyce Polymer, 2007, 48, 1410.
M. E. Wright, B. J. Petteys, A. J. Guenthner, S. Fallis, G. R. Yandek, S. J. Tomczak, T. K. Minton, A. Brunsvold Macromolecules, 2006, 39, 4710.
G. Pan, J. E. Mark, D. W. Schaefer J. Polym. Sci., Part B: Polym. Phys., 2003, 41, 3314.
J. Mu, Y. Liu, S. Zheng Polymer, 2007, 48, 1176.
A. Strachota, I. Kroutilova, J. Kovarova, L. Matejka Macromolecules, 2004, 37, 9457.
A. Tsuchida, C. Bolln, F. G. Sernetz, H. Frey, R. Mülhaupt Macromolecules, 1997, 30, 2818.
J. Wang, Z. Ye, H. Joly Macromolecules, 2007, 40, 6150.
N. E. Markovic, M. Ginic-Markovic, S. Clarke, J. Matisons, M. Hussain, G. P. Simon Macromolecules, 2007, 40, 2694.
W. Xu, Ch. Chung, Y. Kwon Polymer, 2007, 48, 6286.
W. Kai, L. Hua, T. Dong, P. Pan, B. Zhu, Y. Inoue Macromol. Chem. Phys., 2008, 209, 1191.
B. H. Yang, H. Y. Xu, C. Li, S. Y. Guang Chin. Chem. Lett., 2007, 18, 960.
Y. Ni, S. Zhang J. Polym. Sci., Part B: Polym. Phys., 2007, 45, 2201.
L. Ricco, S. Russo, O. Monticelli, A. Bordo, F. Bellucci Polymer, 2005, 46, 6810.
J. Xu, W. Shi Polymer, 2006, 47, 5161.
A. Fina, D. Tabuani, T. Peijs, G. Camino Polymer, 2009, 50, 218.
B. Lepoittevin, N. Pantoustier, M. Devalckenaere, M. Alexandre, D. Kubies, C. Calberg, R. Jerome, Ph. Dubois Macromolecules, 2002, 35, 8385.
G. Carrot, D. Rutot-Houze, A. Pottier, Ph. Degée, J. Hilborn, Ph. Dubois Macromolecules, 2002, 35, 8400.
J. Pyun, K. Matyjaszewski, J. Wu, G.-M. Kim, S. B. Chun, P. T. Mather Polymer, 2003, 44, 2739.
G. S. Constable, A. J. Lesser, E. B. Coughlin Macromolecules, 2004, 37, 1276.
Y. Ni, S. Zheng Macromolecules, 2007, 40, 7009.
Y. Liu, X. Yang, W. Zhang, S. Zheng Polymer, 2006, 47, 6814.
K. Zeng, L. Wang, S. Zheng, X. Qian Polymer, 2009, 50, 685.
H. Hu, D. L. Dorset Macromolecules, 1990, 23, 4604.
H. E. Miltner, Ph.D. Thesis, Vrije Universiteit of Brussel, Belgium, 2008
H. E. Miltner, S. Peterbroek, P. Viville, Ph. Dubois, B. Van Mele J. Polym. Sci., Part B: Polym. Phys., 2007, 45, 1291.
H. E. Miltner, G. Van Assche, A. Pozsgay, B. Pukanszky, B. Van Mele Polymer, 2006, 47, 826.
H. E. Miltner, N. Watzeels, N.-A. Gotzen, G. Van Assche, B. Goderis, A.-L. Goffin, E. Duquesne, S. Benali, B. Ruelle, S. Peeterbroeck, Ph. Dubois, B. Van Mele, in preparation
W. Hamley, V. Castelletto, R. V. Castillo, A. J. Muller, C. M. Martin, E. Pollet, Ph. Dubois Macromolecules, 2005, 38, 463.
M. Murariu, A. Da Silva Ferreira, M. Pluta, L. Bonnaud, M. Alexandre, Ph. Dubois Polym. Adv. Technol., 2008, 19, 636.
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